Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis
The facile pyrolysis of a bipyridyl metal‐organic framework, MOF‐253, produces N‐doped porous carbons (Cz‐MOF‐253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen‐containing MOF‐derived carbons. More importantly, by virtue of their h...
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| Veröffentlicht in: | Chemistry : a European journal 2017-03, Vol.23 (18), p.4266-4270 |
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| container_title | Chemistry : a European journal |
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| creator | Li, Xinle Zhang, Biying Fang, Yuhui Sun, Weijun Qi, Zhiyuan Pei, Yuchen Qi, Shuyan Yuan, Pengyu Luan, Xuechen Goh, Tian Wei Huang, Wenyu |
| description | The facile pyrolysis of a bipyridyl metal‐organic framework, MOF‐253, produces N‐doped porous carbons (Cz‐MOF‐253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen‐containing MOF‐derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz‐MOF‐253‐supported Pd nanoparticles (Pd/Cz‐MOF‐253‐800) show excellent performance in a one‐pot sequential Knoevenagel condensation‐hydrogenation reaction.
Double duty: MOF‐derived carbons with high nitrogen contents are used as solid‐base catalysts and as the support for Pd nanoparticles in tandem catalysis. |
| doi_str_mv | 10.1002/chem.201605852 |
| format | Article |
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Double duty: MOF‐derived carbons with high nitrogen contents are used as solid‐base catalysts and as the support for Pd nanoparticles in tandem catalysis.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201605852</identifier><identifier>PMID: 28188655</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Basicity ; Carbon ; Catalysis ; Catalysts ; Chemistry ; Condensation ; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; Knoevenagel condensation ; MATERIALS SCIENCE ; metal–organic frameworks ; n-doped carbons ; Nanoparticles ; Nitrogen ; palladium ; Pyrolysis ; tandem catalysis</subject><ispartof>Chemistry : a European journal, 2017-03, Vol.23 (18), p.4266-4270</ispartof><rights>2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5762-2df61255472757195cd1acd9db0b6ed2cb6371df66659adf403b2d79006357893</citedby><cites>FETCH-LOGICAL-c5762-2df61255472757195cd1acd9db0b6ed2cb6371df66659adf403b2d79006357893</cites><orcidid>0000-0003-2327-7259 ; 0000000323277259</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201605852$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201605852$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,776,780,881,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28188655$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/servlets/purl/1357787$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Xinle</creatorcontrib><creatorcontrib>Zhang, Biying</creatorcontrib><creatorcontrib>Fang, Yuhui</creatorcontrib><creatorcontrib>Sun, Weijun</creatorcontrib><creatorcontrib>Qi, Zhiyuan</creatorcontrib><creatorcontrib>Pei, Yuchen</creatorcontrib><creatorcontrib>Qi, Shuyan</creatorcontrib><creatorcontrib>Yuan, Pengyu</creatorcontrib><creatorcontrib>Luan, Xuechen</creatorcontrib><creatorcontrib>Goh, Tian Wei</creatorcontrib><creatorcontrib>Huang, Wenyu</creatorcontrib><creatorcontrib>Ames Laboratory (AMES), Ames, IA (United States)</creatorcontrib><title>Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>The facile pyrolysis of a bipyridyl metal‐organic framework, MOF‐253, produces N‐doped porous carbons (Cz‐MOF‐253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen‐containing MOF‐derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz‐MOF‐253‐supported Pd nanoparticles (Pd/Cz‐MOF‐253‐800) show excellent performance in a one‐pot sequential Knoevenagel condensation‐hydrogenation reaction.
Double duty: MOF‐derived carbons with high nitrogen contents are used as solid‐base catalysts and as the support for Pd nanoparticles in tandem catalysis.</description><subject>Basicity</subject><subject>Carbon</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Condensation</subject><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>Knoevenagel condensation</subject><subject>MATERIALS SCIENCE</subject><subject>metal–organic frameworks</subject><subject>n-doped carbons</subject><subject>Nanoparticles</subject><subject>Nitrogen</subject><subject>palladium</subject><subject>Pyrolysis</subject><subject>tandem catalysis</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqN0T9v1DAAh2ELgehRWBmRBQtLDv-J7ZitHC1FailSy2w5tkNdkji1HarburIh8Q37SfDp2iKxwBRHevxK1g-A5xgtMULkjTl3w5IgzBFrGHkAFpgRXFHB2UOwQLIWFWdU7oAnKV0ghCSn9DHYIQ1uGs7YAvw4dln3N9e_TuJXPXpzc_3zIOrBXYX4rZzfu-i_OwtXOrZhTG_h3jT13ujsyx_UCZ6G3tsC3-nkiiqtdcpQjxaeztMUYoZdiPCzhZ_0GCYdsze9S9CP8KwgN9zd8ekpeNTpPrlnt99d8OVg_2x1WB2dfPi42juqDBOcVMR2HBPGakEEE1gyY7E2VtoWtdxZYlpOBS6Icya17WpEW2KFRIhTJhpJd8HLbTek7FUyPjtzbsI4OpMVLkY0oqDXWzTFcDm7lNXgk3F9r0cX5qRwCW2SjP4H5aJMUDNU6Ku_6EWY41heW1SDOW2wrItabpWJIaXoOjVFP-i4VhipzehqM7q6H71ceHGbndvB2Xt-t3IBcguufO_W_8ip1eH-8Z_4b2unu-M</recordid><startdate>20170328</startdate><enddate>20170328</enddate><creator>Li, Xinle</creator><creator>Zhang, Biying</creator><creator>Fang, Yuhui</creator><creator>Sun, Weijun</creator><creator>Qi, Zhiyuan</creator><creator>Pei, Yuchen</creator><creator>Qi, Shuyan</creator><creator>Yuan, Pengyu</creator><creator>Luan, Xuechen</creator><creator>Goh, Tian Wei</creator><creator>Huang, Wenyu</creator><general>Wiley Subscription Services, Inc</general><general>ChemPubSoc Europe</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0003-2327-7259</orcidid><orcidid>https://orcid.org/0000000323277259</orcidid></search><sort><creationdate>20170328</creationdate><title>Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis</title><author>Li, Xinle ; Zhang, Biying ; Fang, Yuhui ; Sun, Weijun ; Qi, Zhiyuan ; Pei, Yuchen ; Qi, Shuyan ; Yuan, Pengyu ; Luan, Xuechen ; Goh, Tian Wei ; Huang, Wenyu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5762-2df61255472757195cd1acd9db0b6ed2cb6371df66659adf403b2d79006357893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Basicity</topic><topic>Carbon</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Condensation</topic><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><topic>Knoevenagel condensation</topic><topic>MATERIALS SCIENCE</topic><topic>metal–organic frameworks</topic><topic>n-doped carbons</topic><topic>Nanoparticles</topic><topic>Nitrogen</topic><topic>palladium</topic><topic>Pyrolysis</topic><topic>tandem catalysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Xinle</creatorcontrib><creatorcontrib>Zhang, Biying</creatorcontrib><creatorcontrib>Fang, Yuhui</creatorcontrib><creatorcontrib>Sun, Weijun</creatorcontrib><creatorcontrib>Qi, Zhiyuan</creatorcontrib><creatorcontrib>Pei, Yuchen</creatorcontrib><creatorcontrib>Qi, Shuyan</creatorcontrib><creatorcontrib>Yuan, Pengyu</creatorcontrib><creatorcontrib>Luan, Xuechen</creatorcontrib><creatorcontrib>Goh, Tian Wei</creatorcontrib><creatorcontrib>Huang, Wenyu</creatorcontrib><creatorcontrib>Ames Laboratory (AMES), Ames, IA (United States)</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Xinle</au><au>Zhang, Biying</au><au>Fang, Yuhui</au><au>Sun, Weijun</au><au>Qi, Zhiyuan</au><au>Pei, Yuchen</au><au>Qi, Shuyan</au><au>Yuan, Pengyu</au><au>Luan, Xuechen</au><au>Goh, Tian Wei</au><au>Huang, Wenyu</au><aucorp>Ames Laboratory (AMES), Ames, IA (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2017-03-28</date><risdate>2017</risdate><volume>23</volume><issue>18</issue><spage>4266</spage><epage>4270</epage><pages>4266-4270</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>The facile pyrolysis of a bipyridyl metal‐organic framework, MOF‐253, produces N‐doped porous carbons (Cz‐MOF‐253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen‐containing MOF‐derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz‐MOF‐253‐supported Pd nanoparticles (Pd/Cz‐MOF‐253‐800) show excellent performance in a one‐pot sequential Knoevenagel condensation‐hydrogenation reaction.
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| subjects | Basicity Carbon Catalysis Catalysts Chemistry Condensation INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Knoevenagel condensation MATERIALS SCIENCE metal–organic frameworks n-doped carbons Nanoparticles Nitrogen palladium Pyrolysis tandem catalysis |
| title | Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis |
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