A Combined Density Functional Theory and Spectrophotometry Study of the Bonding Interactions of [NpO2·M]4+ Cation–Cation Complexes

The equilibrium constants for [NpO2·M]4+ (M = Al3+, In3+, Sc3+, Fe3+) in μ = 10 M nitric acid and [NpO2·Ga]4+ in μ = 10 M hydrochloric acid media have been determined. The trend in the interaction strength follows: Fe3+ > Sc3+ ≥ In3+ > Ga3+ ≫ Al3+. These equilibrium constants are compared to t...

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Veröffentlicht in:	Inorganic chemistry 2017-05, Vol.56 (9), p.4788-4795
Hauptverfasser:	Freiderich, John W, Burn, Adam G, Martin, Leigh R, Nash, Kenneth L, Clark, Aurora E
Format:	Artikel
Sprache:	eng
Schlagworte:	cation-cation density functional theory high ionic strength INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY neptunium spectrophotometry
Online-Zugang:	Volltext
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