Atomic Layer Deposition in a Metal–Organic Framework: Synthesis, Characterization, and Performance of a Solid Acid

NU-1000, a zirconium-based metal–organic framework (MOF) featuring mesoporous channels, has been postsynthetically metalated via atomic layer deposition in a MOF (AIM) employing dimethylaluminum iso-propoxide ([AlMe2O i Pr]2, DMAI), a milder precursor than widely used trimethylaluminum (AlMe3, TMA)....

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Veröffentlicht in:	Chemistry of materials 2017-02, Vol.29 (3), p.1058-1068
Hauptverfasser:	Rimoldi, Martino, Bernales, Varinia, Borycz, Joshua, Vjunov, Aleksei, Gallington, Leighanne C, Platero-Prats, Ana E, Kim, I. S, Fulton, John L, Martinson, A. B. F, Lercher, Johannes A, Chapman, Karena W, Cramer, Christopher J, Gagliardi, Laura, Hupp, Joseph T, Farha, Omar K
Format:	Artikel
Sprache:	eng
Schlagworte:	alumina aluminum atomic layer deposition ethanol dehydration INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY MATERIALS SCIENCE metal-organic framework
Online-Zugang:	Volltext
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