A supramolecular microenvironment strategy for transition metal catalysis

A self-assembled supramolecular complex is reported to catalyze alkyl-alkyl reductive elimination from high-valent transition metal complexes [such as gold(III) and platinum(IV)], the central bond-forming elementary step in many catalytic processes. The catalytic microenvironment of the supramolecul...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2015-12, Vol.350 (6265), p.1235-1238
Hauptverfasser:	Kaphan, David M., Levin, Mark D., Bergman, Robert G., Raymond, Kenneth N., Toste, F. Dean
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Catalysis Catalysts Chemical bonds Enzymes Metals Molecules Rate constants Strategy Transition metals
Online-Zugang:	Volltext
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