Graft-through Synthesis and Assembly of Janus Bottlebrush Polymers from A-Branch-B Diblock Macromonomers

We report the synthesis of Janus bottlebrush block copolymers by graft-through polymerization of branched diblock macromonomers. Self-assembly of the bottlebrushes was characterized by small-angle X-ray scattering, atomic force microscopy, and scanning electron microscopy. Phase separation and packi...

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Veröffentlicht in:Journal of the American Chemical Society 2016-09, Vol.138 (36), p.11501-11504
Hauptverfasser: Kawamoto, Ken, Zhong, Mingjiang, Gadelrab, Karim R, Cheng, Li-Chen, Ross, Caroline A, Alexander-Katz, Alfredo, Johnson, Jeremiah A
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Sprache:eng
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