Strengthening of the Coordination Shell by Counter Ions in Aqueous Th 4+ Solutions

The presence of counterions in solutions containing highly charged metal cations can trigger processes such as ion-pair formation, hydrogen bond breakages and subsequent re-formation, and ligand exchanges. In this work, it is shown how halide (Cl , Br ) and perchlorate (ClO ) anions affect the stren...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2016-12, Vol.120 (51), p.10216-10222
Hauptverfasser: Atta-Fynn, Raymond, Bylaska, Eric J, de Jong, Wibe A
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Sprache:eng
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