Evaluating bis(2-ethylhexyl) methanediphosphonic acid (H2DEH[MDP]) based polymer ligand film (PLF) for plutonium and uranium extraction
This paper describes a new analyte extraction medium called polymer ligand film (PLF) that was developed to rapidly extract radionuclides. PLF is a polymer medium with ligands incorporated in its matrix that selectively and quickly extracts analytes. The main focus of the new technique is to shorten...
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| Veröffentlicht in: | Journal of radioanalytical and nuclear chemistry 2015-09, Vol.307 (3) |
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| container_title | Journal of radioanalytical and nuclear chemistry |
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| creator | Rim, Jung H. Armenta, Claudine E. Gonzales, Edward R. Unlu, Kenan Peterson, Dominic S. |
| description | This paper describes a new analyte extraction medium called polymer ligand film (PLF) that was developed to rapidly extract radionuclides. PLF is a polymer medium with ligands incorporated in its matrix that selectively and quickly extracts analytes. The main focus of the new technique is to shorten and simplify the procedure for chemically isolating radionuclides for determination through alpha spectroscopy. The PLF system was effective for plutonium and uranium extraction. The PLF was capable of co-extracting or selectively extracting plutonium over uranium depending on the PLF composition. As a result, the PLF and electrodeposited samples had similar alpha spectra resolutions. |
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(LANL), Los Alamos, NM (United States)</creatorcontrib><title>Evaluating bis(2-ethylhexyl) methanediphosphonic acid (H2DEH[MDP]) based polymer ligand film (PLF) for plutonium and uranium extraction</title><title>Journal of radioanalytical and nuclear chemistry</title><description>This paper describes a new analyte extraction medium called polymer ligand film (PLF) that was developed to rapidly extract radionuclides. PLF is a polymer medium with ligands incorporated in its matrix that selectively and quickly extracts analytes. The main focus of the new technique is to shorten and simplify the procedure for chemically isolating radionuclides for determination through alpha spectroscopy. The PLF system was effective for plutonium and uranium extraction. The PLF was capable of co-extracting or selectively extracting plutonium over uranium depending on the PLF composition. As a result, the PLF and electrodeposited samples had similar alpha spectra resolutions.</description><subject>actinide</subject><subject>extraction</subject><subject>H2DEH[MDP]</subject><subject>MATERIALS SCIENCE</subject><subject>PLF</subject><subject>plutonium</subject><subject>uranium</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNi0FqwzAUREVoIG7SO3y6shcGWSK2sm4cvGghi-5KCIosx7_IkrHkEp-g165beoAshpnHzCxIlG2FSFkh6AOJKON5ui14tiKP3n9SSndC8Ih8l1_SjDKgvcIFfcxSHdrJtPo2mQS6GaTVNfat87MsKpAKa4grti-rj7f98ZTARXpdQ-_M1OkBDF6lraFB00F8fD0k0LgBejOG-T528FuOg_zL-hYGqQI6uyHLRhqvn_59TZ4P5ftLlTof8OwVBq1a5azVKpwzznZ5kfO7Rj97qlNq</recordid><startdate>20150912</startdate><enddate>20150912</enddate><creator>Rim, Jung H.</creator><creator>Armenta, Claudine E.</creator><creator>Gonzales, Edward R.</creator><creator>Unlu, Kenan</creator><creator>Peterson, Dominic S.</creator><general>Springer</general><scope>OIOZB</scope><scope>OTOTI</scope></search><sort><creationdate>20150912</creationdate><title>Evaluating bis(2-ethylhexyl) methanediphosphonic acid (H2DEH[MDP]) based polymer ligand film (PLF) for plutonium and uranium extraction</title><author>Rim, Jung H. ; Armenta, Claudine E. ; Gonzales, Edward R. ; Unlu, Kenan ; Peterson, Dominic S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_13296763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>actinide</topic><topic>extraction</topic><topic>H2DEH[MDP]</topic><topic>MATERIALS SCIENCE</topic><topic>PLF</topic><topic>plutonium</topic><topic>uranium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rim, Jung H.</creatorcontrib><creatorcontrib>Armenta, Claudine E.</creatorcontrib><creatorcontrib>Gonzales, Edward R.</creatorcontrib><creatorcontrib>Unlu, Kenan</creatorcontrib><creatorcontrib>Peterson, Dominic S.</creatorcontrib><creatorcontrib>Los Alamos National Lab. 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The PLF was capable of co-extracting or selectively extracting plutonium over uranium depending on the PLF composition. As a result, the PLF and electrodeposited samples had similar alpha spectra resolutions.</abstract><cop>United States</cop><pub>Springer</pub><oa>free_for_read</oa></addata></record> |
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| issn | 0236-5731 1588-2780 |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | actinide extraction H2DEH[MDP] MATERIALS SCIENCE PLF plutonium uranium |
| title | Evaluating bis(2-ethylhexyl) methanediphosphonic acid (H2DEH[MDP]) based polymer ligand film (PLF) for plutonium and uranium extraction |
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