More sustainable electricity generation in hot and dry fuel cells with a novel hybrid membrane of Nafion/nano-silica/hydroxyl ionic liquid

Anhydrous hydrogen-bond network in a nano-SiO2 doped Nafion fused by a hydroxyl functionalized ionic liquid for high-performance intermediate-temperature proton exchanging membranes. [Display omitted] •Novel intermediate temperature Nafion based PEMs humidified by a hydroxyl functionalized ionic liquid (IL-OH).•Sulfonated polymer based PEM with an anhydrous hydrogen-bond network crosslinked by IL-OH.•Doping Nafion with IL-OH and nano-SiO2 shows a synergistic enhancement to the mechanical stability.•High conductivity Nafion based PEMs with a large proton transfer number at High temperatures.•H2–O2 fuel cells deliver a power density of 420mWcm−2 at 180°C. A new hybrid proton exchange membrane (PEM) has been prepared from hydroxyl functionalized imidazolium ionic liquid (IL-OH), Nafion and nano-SiO2. The IL-OH, with a hydroxyl group that acts as both a proton acceptor and donor, forms strong hydrogen bonds with both Nafion and nano-SiO2, resulting in an effective hydrogen bond network in the ternary membrane. Such an anhydrous hydrogen-bond network, which is unknown previously, endows the PEMs with higher proton conductivity, greater thermal stability and surprisingly a more robust mechanical performance than PEMs consisting of conventional ionic liquids. The resulting PEMs have a tensile strength that is more than twice as strong as recast Nafion and an anhydrous ionic conductivity of ∼55mScm−1 at temperatures above 160°C, with a proton transfer number of ∼0.9. A laboratory assembled H2–O2 fuel cell employing this new PEM delivered a power density of 340 and 420mWcm−2 at 160 and 180°C, respectively.