Ultralow thermal conductivity of β-Cu2Se by atomic fluidity and structure distortion
We demonstrate a prototype thermal evolution path for liquid thermal conductivity in solids. Thermal evolution of β-Cu2Se shows large interstitial displacement of constituent atoms marked by glass-like transitions and an asymptotic liquid thermal transport. Using ab initio molecular dynamics (AIMD),...
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| Veröffentlicht in: | Acta materialia 2015-03, Vol.86 (C), p.247-253 |
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| container_title | Acta materialia |
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| creator | Kim, Hyoungchul Ballikaya, Sedat Chi, Hang Ahn, Jae-Pyung Ahn, Kiyong Uher, Ctirad Kaviany, Massoud |
| description | We demonstrate a prototype thermal evolution path for liquid thermal conductivity in solids. Thermal evolution of β-Cu2Se shows large interstitial displacement of constituent atoms marked by glass-like transitions and an asymptotic liquid thermal transport. Using ab initio molecular dynamics (AIMD), we identify these transitions, and confirm them with in situ transmission electron microscopy and electron energy loss spectroscopy. The thermal disorder of the Cu+ ions forms homopolar Cu–Cu bonds under a rigid Se framework, and at yet higher temperatures the Se framework undergoes thermal distortion. The non-equilibrium AIMD prediction of lattice thermal conductivity shows significant suppression of the phonon transport, in agreement with experiments and molecular behavior. |
| doi_str_mv | 10.1016/j.actamat.2014.12.008 |
| format | Article |
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Thermal evolution of β-Cu2Se shows large interstitial displacement of constituent atoms marked by glass-like transitions and an asymptotic liquid thermal transport. Using ab initio molecular dynamics (AIMD), we identify these transitions, and confirm them with in situ transmission electron microscopy and electron energy loss spectroscopy. The thermal disorder of the Cu+ ions forms homopolar Cu–Cu bonds under a rigid Se framework, and at yet higher temperatures the Se framework undergoes thermal distortion. 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| ispartof | Acta materialia, 2015-03, Vol.86 (C), p.247-253 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Phonon engineering Structure evolution Thermal conductivity Thermoelectrics Thermophysical property |
| title | Ultralow thermal conductivity of β-Cu2Se by atomic fluidity and structure distortion |
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