Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000
Metal-organic frameworks (MOFs) are porous, crystalline materials with well-defined structures that can be used in many applications, from gas storage to catalysis and drug storage. This protocol is for the preparation of the MOF NU-1000. The synthesis of NU-1000, a highly robust mesoporous (contain...
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| Veröffentlicht in: | Nature protocols 2016-01, Vol.11 (1), p.149-162 |
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| creator | Wang, Timothy C Vermeulen, Nicolaas A Kim, In Soo Martinson, Alex B F Stoddart, J Fraser Hupp, Joseph T Farha, Omar K |
| description | Metal-organic frameworks (MOFs) are porous, crystalline materials with well-defined structures that can be used in many applications, from gas storage to catalysis and drug storage. This protocol is for the preparation of the MOF NU-1000.
The synthesis of NU-1000, a highly robust mesoporous (containing pores >2 nm) metal-organic framework (MOF), can be conducted efficiently on a multigram scale from inexpensive starting materials. Tetrabromopyrene and (4-(ethoxycarbonyl)phenyl)boronic acid can easily be coupled to prepare the requisite organic strut with four metal-binding sites in the form of four carboxylic acids, while zirconyl chloride octahydrate is used as a precursor for the well-defined metal oxide clusters. NU-1000 has been reported as an excellent candidate for the separation of gases, and it is a versatile scaffold for heterogeneous catalysis. In particular, it is ideal for the catalytic deactivation of nerve agents, and it shows great promise as a new generic platform for a wide range of applications. Multiple post-synthetic modification protocols have been developed using NU-1000 as the parent material, making it a potentially useful scaffold for several catalytic applications. The procedure for the preparation of NU-1000 can be scaled up reliably, and it is suitable for the production of 50 g of the tetracarboxylic acid containing organic linker and 200 mg–2.5 g of NU-1000. The entire synthesis is performed without purification by column chromatography and can be completed within 10 d. |
| doi_str_mv | 10.1038/nprot.2016.001 |
| format | Article |
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The synthesis of NU-1000, a highly robust mesoporous (containing pores >2 nm) metal-organic framework (MOF), can be conducted efficiently on a multigram scale from inexpensive starting materials. Tetrabromopyrene and (4-(ethoxycarbonyl)phenyl)boronic acid can easily be coupled to prepare the requisite organic strut with four metal-binding sites in the form of four carboxylic acids, while zirconyl chloride octahydrate is used as a precursor for the well-defined metal oxide clusters. NU-1000 has been reported as an excellent candidate for the separation of gases, and it is a versatile scaffold for heterogeneous catalysis. In particular, it is ideal for the catalytic deactivation of nerve agents, and it shows great promise as a new generic platform for a wide range of applications. Multiple post-synthetic modification protocols have been developed using NU-1000 as the parent material, making it a potentially useful scaffold for several catalytic applications. The procedure for the preparation of NU-1000 can be scaled up reliably, and it is suitable for the production of 50 g of the tetracarboxylic acid containing organic linker and 200 mg–2.5 g of NU-1000. The entire synthesis is performed without purification by column chromatography and can be completed within 10 d.</description><identifier>ISSN: 1754-2189</identifier><identifier>EISSN: 1750-2799</identifier><identifier>DOI: 10.1038/nprot.2016.001</identifier><identifier>PMID: 26678084</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/301/930/1032 ; 639/638/298 ; 639/638/549 ; 639/638/77/887 ; Analytical Chemistry ; Biological Techniques ; Carboxylic acids ; Catalysis ; Chemical synthesis ; Chemistry Techniques, Synthetic - instrumentation ; Chemistry Techniques, Synthetic - methods ; Computational Biology/Bioinformatics ; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; Life Sciences ; mesoporous ; Metal-organic framework ; Metals ; Methods ; Microarrays ; Models, Molecular ; Molecular Conformation ; NU-1000 ; Organic Chemistry ; Organometallic compounds ; Organometallic Compounds - chemical synthesis ; Organometallic Compounds - chemistry ; Porosity ; Properties ; protocol</subject><ispartof>Nature protocols, 2016-01, Vol.11 (1), p.149-162</ispartof><rights>Springer Nature Limited 2015</rights><rights>COPYRIGHT 2016 Nature Publishing Group</rights><rights>Copyright Nature Publishing Group Jan 2016</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c593t-219dd582c75024e61a6eaf8ab0439dec834ca8a6b286a84c7480a6c9c30af6e53</citedby><cites>FETCH-LOGICAL-c593t-219dd582c75024e61a6eaf8ab0439dec834ca8a6b286a84c7480a6c9c30af6e53</cites><orcidid>0000-0002-2736-2488 ; 0000000227362488</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1038/nprot.2016.001$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1038/nprot.2016.001$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,776,780,881,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26678084$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/servlets/purl/1249523$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Timothy C</creatorcontrib><creatorcontrib>Vermeulen, Nicolaas A</creatorcontrib><creatorcontrib>Kim, In Soo</creatorcontrib><creatorcontrib>Martinson, Alex B F</creatorcontrib><creatorcontrib>Stoddart, J Fraser</creatorcontrib><creatorcontrib>Hupp, Joseph T</creatorcontrib><creatorcontrib>Farha, Omar K</creatorcontrib><creatorcontrib>Argonne National Laboratory (ANL), Argonne, IL (United States)</creatorcontrib><title>Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000</title><title>Nature protocols</title><addtitle>Nat Protoc</addtitle><addtitle>Nat Protoc</addtitle><description>Metal-organic frameworks (MOFs) are porous, crystalline materials with well-defined structures that can be used in many applications, from gas storage to catalysis and drug storage. This protocol is for the preparation of the MOF NU-1000.
The synthesis of NU-1000, a highly robust mesoporous (containing pores >2 nm) metal-organic framework (MOF), can be conducted efficiently on a multigram scale from inexpensive starting materials. Tetrabromopyrene and (4-(ethoxycarbonyl)phenyl)boronic acid can easily be coupled to prepare the requisite organic strut with four metal-binding sites in the form of four carboxylic acids, while zirconyl chloride octahydrate is used as a precursor for the well-defined metal oxide clusters. NU-1000 has been reported as an excellent candidate for the separation of gases, and it is a versatile scaffold for heterogeneous catalysis. In particular, it is ideal for the catalytic deactivation of nerve agents, and it shows great promise as a new generic platform for a wide range of applications. Multiple post-synthetic modification protocols have been developed using NU-1000 as the parent material, making it a potentially useful scaffold for several catalytic applications. The procedure for the preparation of NU-1000 can be scaled up reliably, and it is suitable for the production of 50 g of the tetracarboxylic acid containing organic linker and 200 mg–2.5 g of NU-1000. The entire synthesis is performed without purification by column chromatography and can be completed within 10 d.</description><subject>639/301/930/1032</subject><subject>639/638/298</subject><subject>639/638/549</subject><subject>639/638/77/887</subject><subject>Analytical Chemistry</subject><subject>Biological Techniques</subject><subject>Carboxylic acids</subject><subject>Catalysis</subject><subject>Chemical synthesis</subject><subject>Chemistry Techniques, Synthetic - instrumentation</subject><subject>Chemistry Techniques, Synthetic - methods</subject><subject>Computational Biology/Bioinformatics</subject><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>Life Sciences</subject><subject>mesoporous</subject><subject>Metal-organic framework</subject><subject>Metals</subject><subject>Methods</subject><subject>Microarrays</subject><subject>Models, Molecular</subject><subject>Molecular Conformation</subject><subject>NU-1000</subject><subject>Organic Chemistry</subject><subject>Organometallic compounds</subject><subject>Organometallic Compounds - 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Academic</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Nature protocols</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Timothy C</au><au>Vermeulen, Nicolaas A</au><au>Kim, In Soo</au><au>Martinson, Alex B F</au><au>Stoddart, J Fraser</au><au>Hupp, Joseph T</au><au>Farha, Omar K</au><aucorp>Argonne National Laboratory (ANL), Argonne, IL (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000</atitle><jtitle>Nature protocols</jtitle><stitle>Nat Protoc</stitle><addtitle>Nat Protoc</addtitle><date>2016-01-01</date><risdate>2016</risdate><volume>11</volume><issue>1</issue><spage>149</spage><epage>162</epage><pages>149-162</pages><issn>1754-2189</issn><eissn>1750-2799</eissn><abstract>Metal-organic frameworks (MOFs) are porous, crystalline materials with well-defined structures that can be used in many applications, from gas storage to catalysis and drug storage. This protocol is for the preparation of the MOF NU-1000.
The synthesis of NU-1000, a highly robust mesoporous (containing pores >2 nm) metal-organic framework (MOF), can be conducted efficiently on a multigram scale from inexpensive starting materials. Tetrabromopyrene and (4-(ethoxycarbonyl)phenyl)boronic acid can easily be coupled to prepare the requisite organic strut with four metal-binding sites in the form of four carboxylic acids, while zirconyl chloride octahydrate is used as a precursor for the well-defined metal oxide clusters. NU-1000 has been reported as an excellent candidate for the separation of gases, and it is a versatile scaffold for heterogeneous catalysis. In particular, it is ideal for the catalytic deactivation of nerve agents, and it shows great promise as a new generic platform for a wide range of applications. Multiple post-synthetic modification protocols have been developed using NU-1000 as the parent material, making it a potentially useful scaffold for several catalytic applications. The procedure for the preparation of NU-1000 can be scaled up reliably, and it is suitable for the production of 50 g of the tetracarboxylic acid containing organic linker and 200 mg–2.5 g of NU-1000. The entire synthesis is performed without purification by column chromatography and can be completed within 10 d.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>26678084</pmid><doi>10.1038/nprot.2016.001</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-2736-2488</orcidid><orcidid>https://orcid.org/0000000227362488</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | 639/301/930/1032 639/638/298 639/638/549 639/638/77/887 Analytical Chemistry Biological Techniques Carboxylic acids Catalysis Chemical synthesis Chemistry Techniques, Synthetic - instrumentation Chemistry Techniques, Synthetic - methods Computational Biology/Bioinformatics INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Life Sciences mesoporous Metal-organic framework Metals Methods Microarrays Models, Molecular Molecular Conformation NU-1000 Organic Chemistry Organometallic compounds Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Porosity Properties protocol |
| title | Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000 |
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