Solidification and loss of hydrostaticity in liquid media used for pressure measurements

We carried out a study of the pressure dependence of the solidification temperature in nine pressure transmitting media that are liquid at ambient temperature, under pressures up to 2.3 GPa. These fluids are 1:1 isopentane/n-pentane, 4:6 light mineral oil/n-pentane, 1:1 isoamyl alcohol/n-pentane, 4:...

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Veröffentlicht in:Review of scientific instruments 2015-12, Vol.86 (12), p.123904-123904
Hauptverfasser: Torikachvili, M S, Kim, S K, Colombier, E, Bud'ko, S L, Canfield, P C
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container_end_page 123904
container_issue 12
container_start_page 123904
container_title Review of scientific instruments
container_volume 86
creator Torikachvili, M S
Kim, S K
Colombier, E
Bud'ko, S L
Canfield, P C
description We carried out a study of the pressure dependence of the solidification temperature in nine pressure transmitting media that are liquid at ambient temperature, under pressures up to 2.3 GPa. These fluids are 1:1 isopentane/n-pentane, 4:6 light mineral oil/n-pentane, 1:1 isoamyl alcohol/n-pentane, 4:1 methanol/ethanol, 1:1 FC72/FC84 (Fluorinert), Daphne 7373, isopentane, and Dow Corning PMX silicone oils 200 and 60,000 cS. We relied on the high sensitivity of the electrical resistivity of Ba(Fe(1-x)Ru(x))2As2 single crystals to the freezing of the pressure media and cross-checked with corresponding anomalies observed in the resistance of the manganin coil that served as the ambient temperature resistive manometer. In addition to establishing the temperature-pressure line separating the liquid (hydrostatic) and frozen (non-hydrostatic) phases, these data permit rough estimates of the freezing pressure of these media at ambient temperature. This pressure establishes the extreme limit for the medium to be considered hydrostatic. For higher applied pressures, the medium has to be treated as non-hydrostatic.
doi_str_mv 10.1063/1.4937478
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source Alma/SFX Local Collection; AIP Journals (American Institute of Physics)
subjects Ambient temperature
electrical resistivity
Ethanol
Freezing
glass transitions
high pressure
hydrostatics
Manganin
Mineral oils
OTHER INSTRUMENTATION
Pressure dependence
Scientific apparatus & instruments
Single crystals
Solidification
Temperature dependence
title Solidification and loss of hydrostaticity in liquid media used for pressure measurements
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