Shedding light on the structure of a photoinduced transient excimer by time-resolved diffraction

Time-resolved single-crystal diffraction performed with synchrotron radiation shows that the 53(1) micros phosphorescent state, generated in the crystalline phase of trimeric {[3,5-(CF3)(2)Pyrazolate]Cu}(3) molecules by exposure to 355 nm of light at 17 K, is due to the formation of an excimer rathe...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Physical review letters 2005-05, Vol.94 (19), p.193003.1-193003.4, Article 193003
Hauptverfasser:	VORONTSOV, Ivan I, KOVALEVSKY, Andrey Yu, CHEN, Yu-Sheng, GRABER, Tim, GEMBICKY, Milan, NOVOZHILOVA, Irina V, OMARY, Mohammad A, COPPENS, Philip
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics Exact sciences and technology Fluorescence and phosphorescence spectra Fluorescence and phosphorescence radiationless transitions, quenching (intersystem crossing, internal conversion) General molecular conformation and symmetry stereochemistry Molecular properties and interactions with photons Multiphoton ionization and excitation to highly excited states (e.g., rydberg states) Multiphoton ionization and excitation to highly excited states (eg, Rydberg states) Photon interactions with molecules Physics Properties of molecules and molecular ions
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!