Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene

An electrophilic, coordinatively unsaturated rhodium complex supported by borate-linked oxazoline, oxazoline-coordinated silylene, and N-heterocyclic carbene donors [{κ(3)-N,Si,C-PhB(Ox(Me2))(Ox(Me2)SiHPh)Im(Mes)}Rh(H)CO][HB(C6F5)3] (, Ox(Me2) = 4,4-dimethyl-2-oxazoline; Im(Mes) = 1-mesitylimidazole...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2015-01, Vol.44 (36), p.15897-15904
Hauptverfasser:	Xu, Songchen, Boschen, Jeffery S, Biswas, Abhranil, Kobayashi, Takeshi, Pruski, Marek, Windus, Theresa L, Sadow, Aaron D
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Carbonyl compounds Deoxygenation Esters Hydrocarbons INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Lewis acid Rhodium Silanes
Online-Zugang:	Volltext
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