Synthesis and Spectroscopy of New Plutonium(III) and -(IV) Molybdates: Comparisons of Electronic Characteristics
Synthesis of a plutonium(III) molybdate bromide, PuMoO4Br(H2O), has been accomplished using hydrothermal techniques in an inert-atmosphere glovebox. The compound is green in color, which is in stark contrast to the typical blue color of plutonium(III) complexes. The unusual color arises from the bro...
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| Veröffentlicht in: | Inorganic chemistry 2014-03, Vol.53 (6), p.3148-3152 |
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| container_title | Inorganic chemistry |
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| creator | Cross, Justin N Cary, Samantha K Stritzinger, Jared T Polinski, Matthew J Albrecht Schmitt, Thomas E |
| description | Synthesis of a plutonium(III) molybdate bromide, PuMoO4Br(H2O), has been accomplished using hydrothermal techniques in an inert-atmosphere glovebox. The compound is green in color, which is in stark contrast to the typical blue color of plutonium(III) complexes. The unusual color arises from the broad charge transfer (CT) spanning from approximately 300 to 500 nm in the UV–vis–near-IR spectra. Repeating the synthesis with an increase in the reaction temperature results in the formation of a plutonium(IV) molybdate, Pu3Mo6O24(H2O)2, which also has a broad CT band and red-shifted f–f transitions. Performing an analogous reaction with neodymium produced a completely different product, [Nd(H2O)3][NdMo12O42]·2H2O, which is built of Silverton-type polyoxometallate clusters. |
| doi_str_mv | 10.1021/ic403116r |
| format | Article |
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The compound is green in color, which is in stark contrast to the typical blue color of plutonium(III) complexes. The unusual color arises from the broad charge transfer (CT) spanning from approximately 300 to 500 nm in the UV–vis–near-IR spectra. Repeating the synthesis with an increase in the reaction temperature results in the formation of a plutonium(IV) molybdate, Pu3Mo6O24(H2O)2, which also has a broad CT band and red-shifted f–f transitions. 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Performing an analogous reaction with neodymium produced a completely different product, [Nd(H2O)3][NdMo12O42]·2H2O, which is built of Silverton-type polyoxometallate clusters.</description><subject>nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)</subject><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNptkU1r3DAQhkVpaDYfh_yBYAqF3YObkSz5o7eybBJDmhTSlN6ELEusgi05kkzZf18lm-TU0wzMM-_MvIPQGYavGAi-MJJCgXHpP6AFZgRyhuHPR7QASDkuy-YQHYXwCABNQctP6JDQEjCjbIGm-52NWxVMyITts_tJyehdkG7aZU5nt-pv9nOYo7NmHpdt265esHzZ_l5lP9yw63oRVfiWrd04CW-Cs-G5bzO86Fgjs_VWeCGjSsVoZDhBB1oMQZ2-xmP0cLn5tb7Ob-6u2vX3m1wUlMS81lDQtG1FKt0wSjDpukbUWEKvNNGikLqiIGpZM9ZrUWksWNf1Zbpe1xR0cYw-73VdGsuDNFHJrXTWpsV48grTBidouYcm755mFSIfTZBqGIRVbg4cM6gpAVZWCV3tUZnsCV5pPnkzCr_jGPjzF_j7FxJ7_io7d6Pq38k32xPwZQ8IGfijm71NVvxH6B-io42A</recordid><startdate>20140317</startdate><enddate>20140317</enddate><creator>Cross, Justin N</creator><creator>Cary, Samantha K</creator><creator>Stritzinger, Jared T</creator><creator>Polinski, Matthew J</creator><creator>Albrecht Schmitt, Thomas E</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>20140317</creationdate><title>Synthesis and Spectroscopy of New Plutonium(III) and -(IV) Molybdates: Comparisons of Electronic Characteristics</title><author>Cross, Justin N ; Cary, Samantha K ; Stritzinger, Jared T ; Polinski, Matthew J ; Albrecht Schmitt, Thomas E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a342t-8f034934727f954212bb9a81c0def2fa3cf740a8c855dfa7f1a5bbd6520f840f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cross, Justin N</creatorcontrib><creatorcontrib>Cary, Samantha K</creatorcontrib><creatorcontrib>Stritzinger, Jared T</creatorcontrib><creatorcontrib>Polinski, Matthew J</creatorcontrib><creatorcontrib>Albrecht Schmitt, Thomas E</creatorcontrib><creatorcontrib>Materials Science of Actinides (MSA)</creatorcontrib><creatorcontrib>Energy Frontier Research Centers (EFRC)</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cross, Justin N</au><au>Cary, Samantha K</au><au>Stritzinger, Jared T</au><au>Polinski, Matthew J</au><au>Albrecht Schmitt, Thomas E</au><aucorp>Materials Science of Actinides (MSA)</aucorp><aucorp>Energy Frontier Research Centers (EFRC)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Spectroscopy of New Plutonium(III) and -(IV) Molybdates: Comparisons of Electronic Characteristics</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2014-03-17</date><risdate>2014</risdate><volume>53</volume><issue>6</issue><spage>3148</spage><epage>3152</epage><pages>3148-3152</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Synthesis of a plutonium(III) molybdate bromide, PuMoO4Br(H2O), has been accomplished using hydrothermal techniques in an inert-atmosphere glovebox. The compound is green in color, which is in stark contrast to the typical blue color of plutonium(III) complexes. The unusual color arises from the broad charge transfer (CT) spanning from approximately 300 to 500 nm in the UV–vis–near-IR spectra. Repeating the synthesis with an increase in the reaction temperature results in the formation of a plutonium(IV) molybdate, Pu3Mo6O24(H2O)2, which also has a broad CT band and red-shifted f–f transitions. Performing an analogous reaction with neodymium produced a completely different product, [Nd(H2O)3][NdMo12O42]·2H2O, which is built of Silverton-type polyoxometallate clusters.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>24601545</pmid><doi>10.1021/ic403116r</doi><tpages>5</tpages></addata></record> |
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| source | ACS Publications |
| subjects | nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly) |
| title | Synthesis and Spectroscopy of New Plutonium(III) and -(IV) Molybdates: Comparisons of Electronic Characteristics |
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