Electrochemical Studies of the Film Formation on Lithium in Propylene Carbonate Solutions under Open‐Circuit Conditions

Electrochemical Studies of the Film Formation on Lithium in Propylene Carbonate Solutions under Open‐Circuit Conditions

The nature of protective surface layers formed on Li in propylene carbonate solutions of LiClO sub 4 and LiAsF sub 6 at open circuit has been investigated by electrochemical pulse measurements. The results are consistent with the fast formation of a compact thin layer resulting from the reaction wit...

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Veröffentlicht in:Journal of the Electrochemical Society 1982-07, Vol.129 (7), p.1422-1429
Hauptverfasser: Geronov, Y., Schwager, F., Muller, R. H.
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ENERGY STORAGE
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container_end_page 1429
container_issue 7
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container_title Journal of the Electrochemical Society
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creator Geronov, Y.
Schwager, F.
Muller, R. H.
description The nature of protective surface layers formed on Li in propylene carbonate solutions of LiClO sub 4 and LiAsF sub 6 at open circuit has been investigated by electrochemical pulse measurements. The results are consistent with the fast formation of a compact thin layer resulting from the reaction with residual water. This layer acts as a solid ionic conductor. Slow corrosion or decomposition processes produce a thicker porous overlayer. 22 ref.--AA
doi_str_mv 10.1149/1.2124177
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title Electrochemical Studies of the Film Formation on Lithium in Propylene Carbonate Solutions under Open‐Circuit Conditions
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