Synthesis of Perfluoroalkyl End-Functionalized Poly(3-hexylthiophene) and the Effect of Fluorinated End Groups on Solar Cell Performance

A series of well-defined perfluoroalkyl end-functionalized poly(3-hexylthiophenes) (P3HT) were synthesized by Stille coupling of stannylated 2-perfluoralkylthiophene with the bromine end of P3HT. The length of the perfluoroalkyl end group was varied from −C4F13 to −C8F17. These polymers were fully c...

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Veröffentlicht in:Macromolecules 2013-01, Vol.46 (1), p.103-112
Hauptverfasser: Mao, Zhenghao, Vakhshouri, Kiarash, Jaye, Cherno, Fischer, Daniel A, Fernando, Roshan, DeLongchamp, Dean M, Gomez, Enrique D, Sauvé, Geneviève
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Sprache:eng
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