The Molecular Pathway to ZIF-7 Microrods Revealed by In Situ Time-Resolved Small- and Wide-Angle X-Ray Scattering, Quick-Scanning Extended X-Ray Absorption Spectroscopy, and DFT Calculations
We present an in situ small‐ and wide‐angle X‐ray scattering (SAXS/WAXS) and quick‐scanning extended X‐ray absorption fine‐structure (QEXAFS) spectroscopy study on the crystallization of the metal–organic framework ZIF‐7. In combination with DFT calculations, the self‐assembly and growth of ZIF‐7 mi...
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| Veröffentlicht in: | Chemistry : a European journal 2013-06, Vol.19 (24), p.7809-7816 |
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| creator | Goesten, Maarten Stavitski, Eli Pidko, Evgeny A. Gücüyener, Canan Boshuizen, Bart Ehrlich, Steven N. Hensen, Emiel J. M. Kapteijn, Freek Gascon, Jorge |
| description | We present an in situ small‐ and wide‐angle X‐ray scattering (SAXS/WAXS) and quick‐scanning extended X‐ray absorption fine‐structure (QEXAFS) spectroscopy study on the crystallization of the metal–organic framework ZIF‐7. In combination with DFT calculations, the self‐assembly and growth of ZIF‐7 microrods together with the chemical function of the crystal growth modulator (diethylamine) are revealed at all relevant length scales, from the atomic to the full crystal size.
X‐ray marks the spot: In situ time‐resolved small‐ and wide‐angle X‐ray scattering and quick‐scanning extended X‐ray absorption spectroscopy was used to study the crystallization of the metal–organic framework ZIF‐7. These studies along with density functional theory calculation show that the self‐assembly mechanism is rather complex (see figure). |
| doi_str_mv | 10.1002/chem.201204638 |
| format | Article |
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X‐ray marks the spot: In situ time‐resolved small‐ and wide‐angle X‐ray scattering and quick‐scanning extended X‐ray absorption spectroscopy was used to study the crystallization of the metal–organic framework ZIF‐7. These studies along with density functional theory calculation show that the self‐assembly mechanism is rather complex (see figure).</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201204638</identifier><identifier>PMID: 23589117</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>60 APPLIED LIFE SCIENCES ; Absorption spectroscopy ; Chemistry ; crystal engineering ; Crystal growth ; Crystallization ; density functional calculations ; Mathematical analysis ; metal-organic frameworks ; Metalorganic compounds ; Self assembly ; Spectrum analysis ; Wide angle X ray scattering ; X-ray absorption spectroscopy ; X-rays</subject><ispartof>Chemistry : a European journal, 2013-06, Vol.19 (24), p.7809-7816</ispartof><rights>Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5378-13b238be674b39db3d4d312627ea7a232e06b163cae5d5f77b7b899539d5f36e3</citedby><cites>FETCH-LOGICAL-c5378-13b238be674b39db3d4d312627ea7a232e06b163cae5d5f77b7b899539d5f36e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201204638$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201204638$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,776,780,881,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23589117$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/1109446$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Goesten, Maarten</creatorcontrib><creatorcontrib>Stavitski, Eli</creatorcontrib><creatorcontrib>Pidko, Evgeny A.</creatorcontrib><creatorcontrib>Gücüyener, Canan</creatorcontrib><creatorcontrib>Boshuizen, Bart</creatorcontrib><creatorcontrib>Ehrlich, Steven N.</creatorcontrib><creatorcontrib>Hensen, Emiel J. M.</creatorcontrib><creatorcontrib>Kapteijn, Freek</creatorcontrib><creatorcontrib>Gascon, Jorge</creatorcontrib><creatorcontrib>Brookhaven National Laboratory (BNL)</creatorcontrib><title>The Molecular Pathway to ZIF-7 Microrods Revealed by In Situ Time-Resolved Small- and Wide-Angle X-Ray Scattering, Quick-Scanning Extended X-Ray Absorption Spectroscopy, and DFT Calculations</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>We present an in situ small‐ and wide‐angle X‐ray scattering (SAXS/WAXS) and quick‐scanning extended X‐ray absorption fine‐structure (QEXAFS) spectroscopy study on the crystallization of the metal–organic framework ZIF‐7. In combination with DFT calculations, the self‐assembly and growth of ZIF‐7 microrods together with the chemical function of the crystal growth modulator (diethylamine) are revealed at all relevant length scales, from the atomic to the full crystal size.
X‐ray marks the spot: In situ time‐resolved small‐ and wide‐angle X‐ray scattering and quick‐scanning extended X‐ray absorption spectroscopy was used to study the crystallization of the metal–organic framework ZIF‐7. These studies along with density functional theory calculation show that the self‐assembly mechanism is rather complex (see figure).</description><subject>60 APPLIED LIFE SCIENCES</subject><subject>Absorption spectroscopy</subject><subject>Chemistry</subject><subject>crystal engineering</subject><subject>Crystal growth</subject><subject>Crystallization</subject><subject>density functional calculations</subject><subject>Mathematical analysis</subject><subject>metal-organic frameworks</subject><subject>Metalorganic compounds</subject><subject>Self assembly</subject><subject>Spectrum analysis</subject><subject>Wide angle X ray scattering</subject><subject>X-ray absorption spectroscopy</subject><subject>X-rays</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFksFv0zAUxiMEYqVw5YgsuHBYih3XdnIspV0rVhhtUdEuluO8rt6SuMTOtv5z_G24dFSIy07Ws3_f5-fnL4peE9wjGCcf9AaqXoJJgvucpk-iDmEJiang7GnUwVlfxJzR7CR64dw1xjjjlD6PThLK0owQ0Yl-LTeAZrYE3ZaqQRfKb-7UDnmLLqfjWKCZ0Y1tbOHQHG5BlVCgfIemNVoY36KlqSCeg7PlbThYVKosY6TqAq1MAfGgvioB_YjnwXChlffQmPrqFH1rjb6Jw05dhxqN7j3URdAfyEHubLP1xoY7tqB9Y522293pH99P4yUaqnLf7J5wL6Nna1U6ePWwdqPv49FyOInPv55Nh4PzWDMq0pjQPKFpDlz0c5oVOS36BSUJTwQooRKaAOY54VQrYAVbC5GLPM2yMLlQUQ60G709-FrnjXTaeNAbbes6NCgJCYMO4-9G7w_QtrE_W3BeVsZpKEtVg22dJEKkGKeCk8dRyhlmOCMsoO_-Q69t29ThtYFiop8lOBOB6h2o8F3ONbCW28ZUqtlJguU-KXKfFHlMShC8ebBt8wqKI_43GgHIDsCdKWH3iJ0cTkazf83jg9Y4D_dHrWpuJBdUMLn6ciY_49XlfH4xkR_pbyN52GE</recordid><startdate>20130610</startdate><enddate>20130610</enddate><creator>Goesten, Maarten</creator><creator>Stavitski, Eli</creator><creator>Pidko, Evgeny A.</creator><creator>Gücüyener, Canan</creator><creator>Boshuizen, Bart</creator><creator>Ehrlich, Steven N.</creator><creator>Hensen, Emiel J. M.</creator><creator>Kapteijn, Freek</creator><creator>Gascon, Jorge</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><general>ChemPubSoc Europe</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>20130610</creationdate><title>The Molecular Pathway to ZIF-7 Microrods Revealed by In Situ Time-Resolved Small- and Wide-Angle X-Ray Scattering, Quick-Scanning Extended X-Ray Absorption Spectroscopy, and DFT Calculations</title><author>Goesten, Maarten ; Stavitski, Eli ; Pidko, Evgeny A. ; Gücüyener, Canan ; Boshuizen, Bart ; Ehrlich, Steven N. ; Hensen, Emiel J. 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X‐ray marks the spot: In situ time‐resolved small‐ and wide‐angle X‐ray scattering and quick‐scanning extended X‐ray absorption spectroscopy was used to study the crystallization of the metal–organic framework ZIF‐7. These studies along with density functional theory calculation show that the self‐assembly mechanism is rather complex (see figure).</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>23589117</pmid><doi>10.1002/chem.201204638</doi><tpages>8</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | 60 APPLIED LIFE SCIENCES Absorption spectroscopy Chemistry crystal engineering Crystal growth Crystallization density functional calculations Mathematical analysis metal-organic frameworks Metalorganic compounds Self assembly Spectrum analysis Wide angle X ray scattering X-ray absorption spectroscopy X-rays |
| title | The Molecular Pathway to ZIF-7 Microrods Revealed by In Situ Time-Resolved Small- and Wide-Angle X-Ray Scattering, Quick-Scanning Extended X-Ray Absorption Spectroscopy, and DFT Calculations |
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