Controlled polymerizations for the synthesis of semiconducting conjugated polymers
Conjugated polymers have been under active development since the 1970s as the active material in organic field-effect transistors (OFETs), photovoltaic devices and the emissive layer in light-emitting diodes (LEDs). Extensive work has been performed to investigate the physics and chemistry of these...
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| Veröffentlicht in: | Polymer chemistry 2011, Vol.2 (11), p.2424-2434 |
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| container_title | Polymer chemistry |
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| creator | Okamoto, Ken Luscombe, Christine K. |
| description | Conjugated polymers have been under active development since the 1970s as the active material in organic field-effect transistors (OFETs), photovoltaic devices and the emissive layer in light-emitting diodes (LEDs). Extensive work has been performed to investigate the physics and chemistry of these materials, and a variety of semiconducting polymers have been synthesized using a range of polymerization techniques. One of the most important key technologies is to obtain a well-controlled polymerization, which provides polymers with narrow polydispersities and defined molecular weights. In this paper, we describe the recent progress on the synthesis of semiconducting polymers as classified as polyphenylenes, polyphenylenevinylenes, polythiophenes, polyfluorene and their block copolymers by the use of controlled polymerizations. |
| doi_str_mv | 10.1039/c1py00171j |
| format | Article |
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| identifier | ISSN: 1759-9954 |
| ispartof | Polymer chemistry, 2011, Vol.2 (11), p.2424-2434 |
| issn | 1759-9954 1759-9962 |
| language | eng |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Active control Block copolymers Devices INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Molecular weight Polydispersity Polymer chemistry Polymerization solar (photovoltaic), electrodes - solar, charge transport, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing) Synthesis |
| title | Controlled polymerizations for the synthesis of semiconducting conjugated polymers |
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