Real Space Mapping of Li-Ion Transport in Amorphous Si Anodes with Nanometer Resolution
The electrical bias driven Li-ion motion in silicon anode materials in thin film battery heterostructures is investigated using electrochemical strain microscopy (ESM), which is a newly developed scanning probe microscopy based characterization method. ESM utilizes the intrinsic link between bias-co...
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| Veröffentlicht in: | Nano letters 2010-09, Vol.10 (9), p.3420-3425 |
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| container_issue | 9 |
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| container_title | Nano letters |
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| creator | Balke, Nina Jesse, Stephen Kim, Yoongu Adamczyk, Leslie Tselev, Alexander Ivanov, Ilia N Dudney, Nancy J Kalinin, Sergei V |
| description | The electrical bias driven Li-ion motion in silicon anode materials in thin film battery heterostructures is investigated using electrochemical strain microscopy (ESM), which is a newly developed scanning probe microscopy based characterization method. ESM utilizes the intrinsic link between bias-controlled Li-ion concentration and molar volume of electrode materials, providing the capability for studies on the sub-20 nm scale, and allows the relationship between Li-ion flow and microstructure to be established. The evolution of Li-ion transport during the battery charging is directly observed. |
| doi_str_mv | 10.1021/nl101439x |
| format | Article |
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ESM utilizes the intrinsic link between bias-controlled Li-ion concentration and molar volume of electrode materials, providing the capability for studies on the sub-20 nm scale, and allows the relationship between Li-ion flow and microstructure to be established. 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ESM utilizes the intrinsic link between bias-controlled Li-ion concentration and molar volume of electrode materials, providing the capability for studies on the sub-20 nm scale, and allows the relationship between Li-ion flow and microstructure to be established. 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| subjects | catalysis (heterogeneous), solar (fuels), energy storage (including batteries and capacitors), hydrogen and fuel cells, electrodes - solar, mechanical behavior, charge transport, materials and chemistry by design, synthesis (novel materials) Condensed matter: structure, mechanical and thermal properties ENERGY STORAGE Exact sciences and technology Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties NANOSCIENCE AND NANOTECHNOLOGY Physics Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) |
| title | Real Space Mapping of Li-Ion Transport in Amorphous Si Anodes with Nanometer Resolution |
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