Studies of a fuel-rich propane flame with photoionization mass spectrometry
Flame-sampling photoionization mass spectrometry, using continuously tunable synchrotron radiation, offers important advantages for studies of flame chemistry. Mole fraction profile measurements for 24 flame species are presented for a fuel-rich low-pressure premixed laminar C 3H 8/O 2/Ar flame. Nea...
Gespeichert in:
| Veröffentlicht in: | Proceedings of the Combustion Institute 2005-01, Vol.30 (1), p.1681-1688 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1688 |
|---|---|
| container_issue | 1 |
| container_start_page | 1681 |
| container_title | Proceedings of the Combustion Institute |
| container_volume | 30 |
| creator | Cool, Terrill A. Nakajima, Koichi Taatjes, Craig A. McIlroy, Andrew Westmoreland, Phillip R. Law, Matthew E. Morel, Aude |
| description | Flame-sampling photoionization mass spectrometry, using continuously tunable synchrotron radiation, offers important advantages for studies of flame chemistry. Mole fraction profile measurements for 24 flame species are presented for a fuel-rich low-pressure premixed laminar C
3H
8/O
2/Ar flame. Near-threshold photoionization efficiency measurements provide selective detection of individual isomers and unambiguous identifications of other flame species of near-equal mass. The absolute molar composition of the allene and propyne isomers of C
3H
4 was determined. Absolute cross-sections for photoionization of C
2H
2, C
2H
4, CH
3OH, C
3H
4 (propyne), CH
3CHO, (CH
3)
2CO, and C
6H
6 were used to determine molecular beam mass discrimination factors valid for ion masses ranging from 26 to 78
amu. |
| doi_str_mv | 10.1016/j.proci.2004.08.103 |
| format | Article |
| fullrecord | <record><control><sourceid>elsevier_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_1062553</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0082078404001560</els_id><sourcerecordid>S0082078404001560</sourcerecordid><originalsourceid>FETCH-LOGICAL-c470t-4a75da45df9cd15d0f26e51416f55c8ec6f8764d563561c3aa0f9acd4b5273213</originalsourceid><addsrcrecordid>eNp9kEtLAzEUhYMoWKu_wE1wP2MyeU0XLqT4woILdT3E5IamdCZDkir115uxrl2dy-Gcj8tB6JKSmhIqrzf1GIPxdUMIr0lbTHaEZrRVrGoU4cflFpxUireLU3SW0oYQpggTM_T8mnfWQ8LBYY3dDrZV9GaNC2_UA2C31T3gL5-LtQ45-DD4b52L4F6nhNMIJsfQQ477c3Ti9DbBxZ_O0fv93dvysVq9PDwtb1eV4YrkimslrObCuoWxVFjiGgmCciqdEKYFI12rJLdCMiGpYVoTt9DG8g_RKNZQNkdXB25I2XfJ-AxmbcIwlFc6SmQjBCshdgiZGFKK4Lox-l7HfUl002jdpvsdrZtG60hbzKl1c2hB-f_TQ5zwMBiwPk50G_y__R8UCHcx</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Studies of a fuel-rich propane flame with photoionization mass spectrometry</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Cool, Terrill A. ; Nakajima, Koichi ; Taatjes, Craig A. ; McIlroy, Andrew ; Westmoreland, Phillip R. ; Law, Matthew E. ; Morel, Aude</creator><creatorcontrib>Cool, Terrill A. ; Nakajima, Koichi ; Taatjes, Craig A. ; McIlroy, Andrew ; Westmoreland, Phillip R. ; Law, Matthew E. ; Morel, Aude ; Cornell Univ., Ithaca, NY (United States)</creatorcontrib><description>Flame-sampling photoionization mass spectrometry, using continuously tunable synchrotron radiation, offers important advantages for studies of flame chemistry. Mole fraction profile measurements for 24 flame species are presented for a fuel-rich low-pressure premixed laminar C
3H
8/O
2/Ar flame. Near-threshold photoionization efficiency measurements provide selective detection of individual isomers and unambiguous identifications of other flame species of near-equal mass. The absolute molar composition of the allene and propyne isomers of C
3H
4 was determined. Absolute cross-sections for photoionization of C
2H
2, C
2H
4, CH
3OH, C
3H
4 (propyne), CH
3CHO, (CH
3)
2CO, and C
6H
6 were used to determine molecular beam mass discrimination factors valid for ion masses ranging from 26 to 78
amu.</description><identifier>ISSN: 1540-7489</identifier><identifier>EISSN: 1873-2704</identifier><identifier>DOI: 10.1016/j.proci.2004.08.103</identifier><language>eng</language><publisher>United States: Elsevier Inc</publisher><subject>10 SYNTHETIC FUELS ; CHEMISTRY ; COMBUSTION ; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; KINETICS ; Mass spectrometry ; OXIDATION ; Photoionization ; Premixed laminar flame</subject><ispartof>Proceedings of the Combustion Institute, 2005-01, Vol.30 (1), p.1681-1688</ispartof><rights>2004 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c470t-4a75da45df9cd15d0f26e51416f55c8ec6f8764d563561c3aa0f9acd4b5273213</citedby><cites>FETCH-LOGICAL-c470t-4a75da45df9cd15d0f26e51416f55c8ec6f8764d563561c3aa0f9acd4b5273213</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.proci.2004.08.103$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/1062553$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Cool, Terrill A.</creatorcontrib><creatorcontrib>Nakajima, Koichi</creatorcontrib><creatorcontrib>Taatjes, Craig A.</creatorcontrib><creatorcontrib>McIlroy, Andrew</creatorcontrib><creatorcontrib>Westmoreland, Phillip R.</creatorcontrib><creatorcontrib>Law, Matthew E.</creatorcontrib><creatorcontrib>Morel, Aude</creatorcontrib><creatorcontrib>Cornell Univ., Ithaca, NY (United States)</creatorcontrib><title>Studies of a fuel-rich propane flame with photoionization mass spectrometry</title><title>Proceedings of the Combustion Institute</title><description>Flame-sampling photoionization mass spectrometry, using continuously tunable synchrotron radiation, offers important advantages for studies of flame chemistry. Mole fraction profile measurements for 24 flame species are presented for a fuel-rich low-pressure premixed laminar C
3H
8/O
2/Ar flame. Near-threshold photoionization efficiency measurements provide selective detection of individual isomers and unambiguous identifications of other flame species of near-equal mass. The absolute molar composition of the allene and propyne isomers of C
3H
4 was determined. Absolute cross-sections for photoionization of C
2H
2, C
2H
4, CH
3OH, C
3H
4 (propyne), CH
3CHO, (CH
3)
2CO, and C
6H
6 were used to determine molecular beam mass discrimination factors valid for ion masses ranging from 26 to 78
amu.</description><subject>10 SYNTHETIC FUELS</subject><subject>CHEMISTRY</subject><subject>COMBUSTION</subject><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>KINETICS</subject><subject>Mass spectrometry</subject><subject>OXIDATION</subject><subject>Photoionization</subject><subject>Premixed laminar flame</subject><issn>1540-7489</issn><issn>1873-2704</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWKu_wE1wP2MyeU0XLqT4woILdT3E5IamdCZDkir115uxrl2dy-Gcj8tB6JKSmhIqrzf1GIPxdUMIr0lbTHaEZrRVrGoU4cflFpxUireLU3SW0oYQpggTM_T8mnfWQ8LBYY3dDrZV9GaNC2_UA2C31T3gL5-LtQ45-DD4b52L4F6nhNMIJsfQQ477c3Ti9DbBxZ_O0fv93dvysVq9PDwtb1eV4YrkimslrObCuoWxVFjiGgmCciqdEKYFI12rJLdCMiGpYVoTt9DG8g_RKNZQNkdXB25I2XfJ-AxmbcIwlFc6SmQjBCshdgiZGFKK4Lox-l7HfUl002jdpvsdrZtG60hbzKl1c2hB-f_TQ5zwMBiwPk50G_y__R8UCHcx</recordid><startdate>20050101</startdate><enddate>20050101</enddate><creator>Cool, Terrill A.</creator><creator>Nakajima, Koichi</creator><creator>Taatjes, Craig A.</creator><creator>McIlroy, Andrew</creator><creator>Westmoreland, Phillip R.</creator><creator>Law, Matthew E.</creator><creator>Morel, Aude</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20050101</creationdate><title>Studies of a fuel-rich propane flame with photoionization mass spectrometry</title><author>Cool, Terrill A. ; Nakajima, Koichi ; Taatjes, Craig A. ; McIlroy, Andrew ; Westmoreland, Phillip R. ; Law, Matthew E. ; Morel, Aude</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c470t-4a75da45df9cd15d0f26e51416f55c8ec6f8764d563561c3aa0f9acd4b5273213</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>10 SYNTHETIC FUELS</topic><topic>CHEMISTRY</topic><topic>COMBUSTION</topic><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><topic>KINETICS</topic><topic>Mass spectrometry</topic><topic>OXIDATION</topic><topic>Photoionization</topic><topic>Premixed laminar flame</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cool, Terrill A.</creatorcontrib><creatorcontrib>Nakajima, Koichi</creatorcontrib><creatorcontrib>Taatjes, Craig A.</creatorcontrib><creatorcontrib>McIlroy, Andrew</creatorcontrib><creatorcontrib>Westmoreland, Phillip R.</creatorcontrib><creatorcontrib>Law, Matthew E.</creatorcontrib><creatorcontrib>Morel, Aude</creatorcontrib><creatorcontrib>Cornell Univ., Ithaca, NY (United States)</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Proceedings of the Combustion Institute</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cool, Terrill A.</au><au>Nakajima, Koichi</au><au>Taatjes, Craig A.</au><au>McIlroy, Andrew</au><au>Westmoreland, Phillip R.</au><au>Law, Matthew E.</au><au>Morel, Aude</au><aucorp>Cornell Univ., Ithaca, NY (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Studies of a fuel-rich propane flame with photoionization mass spectrometry</atitle><jtitle>Proceedings of the Combustion Institute</jtitle><date>2005-01-01</date><risdate>2005</risdate><volume>30</volume><issue>1</issue><spage>1681</spage><epage>1688</epage><pages>1681-1688</pages><issn>1540-7489</issn><eissn>1873-2704</eissn><abstract>Flame-sampling photoionization mass spectrometry, using continuously tunable synchrotron radiation, offers important advantages for studies of flame chemistry. Mole fraction profile measurements for 24 flame species are presented for a fuel-rich low-pressure premixed laminar C
3H
8/O
2/Ar flame. Near-threshold photoionization efficiency measurements provide selective detection of individual isomers and unambiguous identifications of other flame species of near-equal mass. The absolute molar composition of the allene and propyne isomers of C
3H
4 was determined. Absolute cross-sections for photoionization of C
2H
2, C
2H
4, CH
3OH, C
3H
4 (propyne), CH
3CHO, (CH
3)
2CO, and C
6H
6 were used to determine molecular beam mass discrimination factors valid for ion masses ranging from 26 to 78
amu.</abstract><cop>United States</cop><pub>Elsevier Inc</pub><doi>10.1016/j.proci.2004.08.103</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1540-7489 |
| ispartof | Proceedings of the Combustion Institute, 2005-01, Vol.30 (1), p.1681-1688 |
| issn | 1540-7489 1873-2704 |
| language | eng |
| recordid | cdi_osti_scitechconnect_1062553 |
| source | Elsevier ScienceDirect Journals Complete |
| subjects | 10 SYNTHETIC FUELS CHEMISTRY COMBUSTION INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY KINETICS Mass spectrometry OXIDATION Photoionization Premixed laminar flame |
| title | Studies of a fuel-rich propane flame with photoionization mass spectrometry |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T05%3A48%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-elsevier_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Studies%20of%20a%20fuel-rich%20propane%20flame%20with%20photoionization%20mass%20spectrometry&rft.jtitle=Proceedings%20of%20the%20Combustion%20Institute&rft.au=Cool,%20Terrill%20A.&rft.aucorp=Cornell%20Univ.,%20Ithaca,%20NY%20(United%20States)&rft.date=2005-01-01&rft.volume=30&rft.issue=1&rft.spage=1681&rft.epage=1688&rft.pages=1681-1688&rft.issn=1540-7489&rft.eissn=1873-2704&rft_id=info:doi/10.1016/j.proci.2004.08.103&rft_dat=%3Celsevier_osti_%3ES0082078404001560%3C/elsevier_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rft_els_id=S0082078404001560&rfr_iscdi=true |