Effect of Ligand Structural Isomerism in Formation of Calcium Coordination Networks
Using different structural isomers (2,5-; 2,4-; 2;6-; 3,4-; 3,5-) of pyridinedicarboxylic acid, nine calcium-based coordination networks were synthesized under hydro-/solvothermal conditions and/or were produced via solvent recrystallization of previously synthesized compounds. The coordination netw...
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| Veröffentlicht in: | Crystal growth & design 2012-05, Vol.12 (5), p.2460-2467 |
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| container_title | Crystal growth & design |
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| creator | Plonka, Anna M Banerjee, Debasis Parise, John B |
| description | Using different structural isomers (2,5-; 2,4-; 2;6-; 3,4-; 3,5-) of pyridinedicarboxylic acid, nine calcium-based coordination networks were synthesized under hydro-/solvothermal conditions and/or were produced via solvent recrystallization of previously synthesized compounds. The coordination networks reported were characterized using single crystal X-ray diffraction and thermal methods. They show diverse structural topologies, depending on the ligand geometry and coordinated solvent molecules, with inorganic connectivity motifs ranging from isolated octahedra to infinite chains, layer and a three-dimensional dense framework. The as-synthesized and desolvated networks further show structural transformation to hydrated phases through dissolution/reformation pathways. The process is likely driven by the high hydration energy of the calcium metal center. |
| doi_str_mv | 10.1021/cg300093h |
| format | Article |
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The coordination networks reported were characterized using single crystal X-ray diffraction and thermal methods. They show diverse structural topologies, depending on the ligand geometry and coordinated solvent molecules, with inorganic connectivity motifs ranging from isolated octahedra to infinite chains, layer and a three-dimensional dense framework. The as-synthesized and desolvated networks further show structural transformation to hydrated phases through dissolution/reformation pathways. 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The process is likely driven by the high hydration energy of the calcium metal center.</description><subject>CALCIUM</subject><subject>Constant-composition solid-solid phase transformations: polymorphic, massive, and order-disorder</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>diffraction</subject><subject>Exact sciences and technology</subject><subject>GEOMETRY</subject><subject>HYDRATION</subject><subject>ISOMERS</subject><subject>MATERIALS SCIENCE</subject><subject>MONOCRYSTALS</subject><subject>national synchrotron light source</subject><subject>Phase diagrams and microstructures developed by solidification and solid-solid phase transformations</subject><subject>Physics</subject><subject>pyridinedicarboxylic</subject><subject>RECRYSTALLIZATION</subject><subject>SOLVENTS</subject><subject>solvothermal</subject><subject>TRANSFORMATIONS</subject><subject>X-RAY DIFFRACTION</subject><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNpt0M1KAzEQAOAgCtbqwTdYBA8eVpPM_h6ltFooeqiel9ls0qbuJiXJIr69W1brReYww_DNwAwh14zeM8rZg9gApbSE7QmZsJQXcZ7S9PS3Tgo4Jxfe7waTZwATsp4rJUWIrIpWeoOmidbB9SL0Dtto6W0nnfZdpE20sK7DoK052Bm2QvddNLPWNdqM_RcZPq378JfkTGHr5dVPnpL3xfxt9hyvXp-Ws8dVjFDwEENT1HQILFLB86zkrAbKgCc0UWleYykpa0DJhmZJoxBEAUpBwhTUDLOmhCm5GfdaH3TlhQ5SbIU1ZjioYjQpeZYP6G5EwlnvnVTV3ukO3dcgqsPLquPLBns72j16ga1yaIT2xwGeFjnPIPtzKHy1s70zw5n_7PsG3v53CQ</recordid><startdate>20120502</startdate><enddate>20120502</enddate><creator>Plonka, Anna M</creator><creator>Banerjee, Debasis</creator><creator>Parise, John B</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20120502</creationdate><title>Effect of Ligand Structural Isomerism in Formation of Calcium Coordination Networks</title><author>Plonka, Anna M ; Banerjee, Debasis ; Parise, John B</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a382t-3d8b0b0ba85c276921b30132404f57ba9e01d3fed064dfa3c83ff341f3b1a6d93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>CALCIUM</topic><topic>Constant-composition solid-solid phase transformations: polymorphic, massive, and order-disorder</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>diffraction</topic><topic>Exact sciences and technology</topic><topic>GEOMETRY</topic><topic>HYDRATION</topic><topic>ISOMERS</topic><topic>MATERIALS SCIENCE</topic><topic>MONOCRYSTALS</topic><topic>national synchrotron light source</topic><topic>Phase diagrams and microstructures developed by solidification and solid-solid phase transformations</topic><topic>Physics</topic><topic>pyridinedicarboxylic</topic><topic>RECRYSTALLIZATION</topic><topic>SOLVENTS</topic><topic>solvothermal</topic><topic>TRANSFORMATIONS</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Plonka, Anna M</creatorcontrib><creatorcontrib>Banerjee, Debasis</creatorcontrib><creatorcontrib>Parise, John B</creatorcontrib><creatorcontrib>Brookhaven National Laboratory (BNL) National Synchrotron Light Source</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Crystal growth & design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Plonka, Anna M</au><au>Banerjee, Debasis</au><au>Parise, John B</au><aucorp>Brookhaven National Laboratory (BNL) National Synchrotron Light Source</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Ligand Structural Isomerism in Formation of Calcium Coordination Networks</atitle><jtitle>Crystal growth & design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2012-05-02</date><risdate>2012</risdate><volume>12</volume><issue>5</issue><spage>2460</spage><epage>2467</epage><pages>2460-2467</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>Using different structural isomers (2,5-; 2,4-; 2;6-; 3,4-; 3,5-) of pyridinedicarboxylic acid, nine calcium-based coordination networks were synthesized under hydro-/solvothermal conditions and/or were produced via solvent recrystallization of previously synthesized compounds. The coordination networks reported were characterized using single crystal X-ray diffraction and thermal methods. They show diverse structural topologies, depending on the ligand geometry and coordinated solvent molecules, with inorganic connectivity motifs ranging from isolated octahedra to infinite chains, layer and a three-dimensional dense framework. The as-synthesized and desolvated networks further show structural transformation to hydrated phases through dissolution/reformation pathways. 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| ispartof | Crystal growth & design, 2012-05, Vol.12 (5), p.2460-2467 |
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| source | American Chemical Society Journals |
| subjects | CALCIUM Constant-composition solid-solid phase transformations: polymorphic, massive, and order-disorder Cross-disciplinary physics: materials science rheology diffraction Exact sciences and technology GEOMETRY HYDRATION ISOMERS MATERIALS SCIENCE MONOCRYSTALS national synchrotron light source Phase diagrams and microstructures developed by solidification and solid-solid phase transformations Physics pyridinedicarboxylic RECRYSTALLIZATION SOLVENTS solvothermal TRANSFORMATIONS X-RAY DIFFRACTION |
| title | Effect of Ligand Structural Isomerism in Formation of Calcium Coordination Networks |
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