Controlling the Nucleation and Growth of Silver on Palladium Nanocubes by Manipulating the Reaction Kinetics

Tell the atoms where to go: By manipulating the rate at which Ag atoms were generated from a precursor, the nucleation and growth of Ag on Pd nanocubes with six equivalent {100} facets were controlled to generate three different types of bimetallic nanocrystals: Pd–Ag hybrid dimers, Pd–Ag eccentric...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2012-03, Vol.51 (10), p.2354-2358
Hauptverfasser:	Zeng, Jie, Zhu, Cun, Tao, Jing, Jin, Mingshang, Zhang, Hui, Li, Zhi-Yuan, Zhu, Yimei, Xia, Younan
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Sprache:	eng
Schlagworte:	ATOMS Bimetals CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY DIMERS Equivalence Kinetics Metal Nanoparticles - chemistry Microscopy, Electron, Transmission Nanocrystals Nanostructure NUCLEATION Nuclei PALLADIUM Palladium - chemistry PHYSICS OF ELEMENTARY PARTICLES AND FIELDS PLASMONS PRECURSOR Precursors REACTION KINETICS RESONANCE seed-mediated growth SILVER Silver - chemistry surface plasmon resonance
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container_title	Angewandte Chemie (International ed.)
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creator	Zeng, Jie Zhu, Cun Tao, Jing Jin, Mingshang Zhang, Hui Li, Zhi-Yuan Zhu, Yimei Xia, Younan
description	Tell the atoms where to go: By manipulating the rate at which Ag atoms were generated from a precursor, the nucleation and growth of Ag on Pd nanocubes with six equivalent {100} facets were controlled to generate three different types of bimetallic nanocrystals: Pd–Ag hybrid dimers, Pd–Ag eccentric nanobars, and Pd@Ag core–shell nanocrystals (see scheme).
doi_str_mv	10.1002/anie.201107061
format	Article
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Ed</addtitle><description>Tell the atoms where to go: By manipulating the rate at which Ag atoms were generated from a precursor, the nucleation and growth of Ag on Pd nanocubes with six equivalent {100} facets were controlled to generate three different types of bimetallic nanocrystals: Pd–Ag hybrid dimers, Pd–Ag eccentric nanobars, and Pd@Ag core–shell nanocrystals (see scheme).</description><subject>ATOMS</subject><subject>Bimetals</subject><subject>CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY</subject><subject>DIMERS</subject><subject>Equivalence</subject><subject>Kinetics</subject><subject>Metal Nanoparticles - chemistry</subject><subject>Microscopy, Electron, Transmission</subject><subject>Nanocrystals</subject><subject>Nanostructure</subject><subject>NUCLEATION</subject><subject>Nuclei</subject><subject>PALLADIUM</subject><subject>Palladium - chemistry</subject><subject>PHYSICS OF ELEMENTARY PARTICLES AND FIELDS</subject><subject>PLASMONS</subject><subject>PRECURSOR</subject><subject>Precursors</subject><subject>REACTION KINETICS</subject><subject>RESONANCE</subject><subject>seed-mediated growth</subject><subject>SILVER</subject><subject>Silver - chemistry</subject><subject>surface plasmon resonance</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUtvEzEURkcIREthyxKN6AI2E_wY2zPLNiqhJQ0VD7G0PJ4b4uLYwfZQ8u9xmBAhFrCyZZ3vyPd-RfEUowlGiLxSzsCEIIyRQBzfK44xI7iiQtD7-V5TWomG4aPiUYy3mW8axB8WR4RgxNqmPi7s1LsUvLXGfSnTCsrFoC2oZLwrlevLWfB3aVX6ZfnB2O8Qyvx-o6xVvRnW5UI5r4cOYtlty-v8l81gc3aveg9K_xK9NQ6S0fFx8WCpbIQn-_Ok-PT64uP0TTV_N7ucns0rzSjHFWlY32tGmp5wCsCJYKAQ71roQBHGesUVNKqGlpJmWXdEa4QV150SdZdBelI8H70-JiOjNgn0SnvnQCeJUV0LsYNejNAm-G8DxCTXJmrIoznwQ5Qt4ZjVeU2ZfPlPEovd_hHFJKOnf6G3fgguDysxw5xz1BCWqclI6eBjDLCUm2DWKmzz5-SuVrmrVR5qzYFne-3QraE_4L97zEA7AnfGwvY_Onm2uLz4U16NWRMT_DhkVfgquaCCyc-LmTy_Ymh-fXUub-hP_Pa9NQ</recordid><startdate>20120305</startdate><enddate>20120305</enddate><creator>Zeng, Jie</creator><creator>Zhu, Cun</creator><creator>Tao, Jing</creator><creator>Jin, Mingshang</creator><creator>Zhang, Hui</creator><creator>Li, Zhi-Yuan</creator><creator>Zhu, Yimei</creator><creator>Xia, Younan</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>20120305</creationdate><title>Controlling the Nucleation and Growth of Silver on Palladium Nanocubes by Manipulating the Reaction Kinetics</title><author>Zeng, Jie ; 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subjects	ATOMS Bimetals CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY DIMERS Equivalence Kinetics Metal Nanoparticles - chemistry Microscopy, Electron, Transmission Nanocrystals Nanostructure NUCLEATION Nuclei PALLADIUM Palladium - chemistry PHYSICS OF ELEMENTARY PARTICLES AND FIELDS PLASMONS PRECURSOR Precursors REACTION KINETICS RESONANCE seed-mediated growth SILVER Silver - chemistry surface plasmon resonance
title	Controlling the Nucleation and Growth of Silver on Palladium Nanocubes by Manipulating the Reaction Kinetics
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