Formate oxidation via β-deprotonation in [Ni(PR2NR′2)2(CH3CN)]2+ complexes

Recent studies from our laboratories have shown that the [Ni(PR2NR'2)2(CH3CN)]2+ complexes originally developed as artificial hydrogenases are also active electrocatalysts for formate oxidation (TOF ~16 s-1). The focus of the current work is to develop a detailed understanding of the catalytic...

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Veröffentlicht in:	Energy & environmental science 2012, Vol.5 (4), p.6480
Hauptverfasser:	Seu, Candace S., Appel, Aaron M., Doud, Michael D., DuBois, Daniel L., Kubiak, Clifford P.
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis CATALYSTS DESIGN electrocatalysis ELECTROCATALYSTS formate oxidation FORMATES HYDRIDES HYDROGENASES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY OXIDATION PROTON TRANSPORT
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