Atmospheric chemistry of cyclohexanone: UV spectrum and kinetics of reaction with chlorine atoms

Absolute and relative rate techniques were used to study the reactivity of Cl atoms with cyclohexanone in 6 Torr of argon or 800–950 Torr of N2 at 295 ± 2 K. The absolute rate experiments gave k(Cl + cyclohexanone) = (1.88 ± 0.38) × 10−10, whereas the relative rate experiments gave k(Cl + cyclohexan...

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Veröffentlicht in:	International journal of chemical kinetics 2008-05, Vol.40 (5), p.223-229
Hauptverfasser:	Iwasaki, E., Matsumi, Y., Takahashi, K., Wallington, T. J., Hurley, M.D., Orlando, J. J., Kaiser, E. W., Calvert, J. G.
Format:	Artikel
Sprache:	eng
Schlagworte:	ABSORPTION ARGON ATMOSPHERIC CHEMISTRY ATOMS CHLORINE CROSS SECTIONS CYCLOHEXANONE ENVIRONMENTAL SCIENCES KINETICS
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