Crystal Structure of Homo-DNA and Nature's Choice of Pentose over Hexose in the Genetic System

An experimental rationalization of the structure type encountered in DNA and RNA by systematically investigating the chemical and physical properties of alternative nucleic acids has identified systems with a variety of sugar−phosphate backbones that are capable of Watson−Crick base pairing and in s...

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Veröffentlicht in:	Journal of the American Chemical Society 2006-08, Vol.128 (33), p.10847-10856
Hauptverfasser:	Egli, Martin, Pallan, Pradeep S, Pattanayek, Rekha, Wilds, Christopher J, Lubini, Paolo, Minasov, George, Dobler, Max, Leumann, Christian J, Eschenmoser, Albert
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical, structural and metabolic biochemistry Biological and medical sciences Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides Carbohydrates. Nucleosides and nucleotides Chemistry CRYSTAL STRUCTURE DNA DNA - chemistry Dna, deoxyribonucleoproteins Exact sciences and technology Fundamental and applied biological sciences. Psychology General and physical chemistry GENETICS HEXOSES Hexoses - chemistry INCLINATION MATERIALS SCIENCE Models, Molecular Nucleic Acid Conformation NUCLEIC ACIDS Nucleosides, nucleotides and oligonucleotides OLIGONUCLEOTIDES Organic chemistry PENTOSES Pentoses - chemistry PHYSICAL PROPERTIES Preparations and properties RNA
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