The effect of the surface of SnO2 nanoribbons on their luminescence using x-ray absorption and luminescence spectroscopy
X-ray excited optical luminescence (XEOL) and x-ray absorption near-edge structure in total electron, x-ray fluorescence, and photoluminescence yields at Sn M5,4-, O K-, and Sn K-edges have been used to study the luminescence from SnO2 nanoribbons. The effect of the surface on the luminescence from...
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Veröffentlicht in: | The Journal of chemical physics 2008-04, Vol.128 (14), p.144703-144703 |
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creator | Zhou, X T Zhou, J G Murphy, M W Ko, J Y P Heigl, F Regier, T Blyth, R I R Sham, T K |
description | X-ray excited optical luminescence (XEOL) and x-ray absorption near-edge structure in total electron, x-ray fluorescence, and photoluminescence yields at Sn M5,4-, O K-, and Sn K-edges have been used to study the luminescence from SnO2 nanoribbons. The effect of the surface on the luminescence from SnO2 nanoribbons was studied by preferential excitation of the ions in the near-surface region and at the normal lattice positions, respectively. No noticeable change of luminescence from SnO2 nanoribbons was observed if the Sn ions in the near-surface region were excited selectively, while the luminescence intensity changes markedly when Sn or O ions at the normal lattice positions were excited across the corresponding edges. Based on the experimental results, we show that the luminescence from SnO2 nanoribbons is dominated by energy transfer from the excitation of the whole SnO2 lattice to the surface states. Surface site specificity is not observable due to its low concentration and weak absorption coefficient although the surface plays an important role in the emission as a luminescence center. The energy transfer and site specificity of the XEOL or the lack of the site specificity from a single-phase sample is discussed. |
doi_str_mv | 10.1063/1.2841419 |
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(ANL), Argonne, IL (United States). Advanced Photon Source (APS)</creatorcontrib><description>X-ray excited optical luminescence (XEOL) and x-ray absorption near-edge structure in total electron, x-ray fluorescence, and photoluminescence yields at Sn M5,4-, O K-, and Sn K-edges have been used to study the luminescence from SnO2 nanoribbons. The effect of the surface on the luminescence from SnO2 nanoribbons was studied by preferential excitation of the ions in the near-surface region and at the normal lattice positions, respectively. No noticeable change of luminescence from SnO2 nanoribbons was observed if the Sn ions in the near-surface region were excited selectively, while the luminescence intensity changes markedly when Sn or O ions at the normal lattice positions were excited across the corresponding edges. Based on the experimental results, we show that the luminescence from SnO2 nanoribbons is dominated by energy transfer from the excitation of the whole SnO2 lattice to the surface states. Surface site specificity is not observable due to its low concentration and weak absorption coefficient although the surface plays an important role in the emission as a luminescence center. The energy transfer and site specificity of the XEOL or the lack of the site specificity from a single-phase sample is discussed.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.2841419</identifier><identifier>PMID: 18412467</identifier><language>eng</language><publisher>United States</publisher><subject>ABSORPTION ; EMISSION ; ENERGY TRANSFER ; EXCITATION ; FLUORESCENCE ; IONS ; LUMINESCENCE ; MATERIALS ; MATERIALS SCIENCE ; NANOSTRUCTURES ; PHOTOLUMINESCENCE ; SEMICONDUCTOR MATERIALS ; SPECIFICITY ; SPECTROSCOPY ; SURFACES ; TIN COMPOUNDS ; X-RAY SPECTRA ; X-RAY SPECTROSCOPY ; YIELDS</subject><ispartof>The Journal of chemical physics, 2008-04, Vol.128 (14), p.144703-144703</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c240t-85eda4fa5df29626bf8e7423fab050730196addf9d4c410597023414aaf5d9813</citedby><cites>FETCH-LOGICAL-c240t-85eda4fa5df29626bf8e7423fab050730196addf9d4c410597023414aaf5d9813</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/18412467$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/1006556$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhou, X T</creatorcontrib><creatorcontrib>Zhou, J G</creatorcontrib><creatorcontrib>Murphy, M W</creatorcontrib><creatorcontrib>Ko, J Y P</creatorcontrib><creatorcontrib>Heigl, F</creatorcontrib><creatorcontrib>Regier, T</creatorcontrib><creatorcontrib>Blyth, R I R</creatorcontrib><creatorcontrib>Sham, T K</creatorcontrib><creatorcontrib>Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)</creatorcontrib><title>The effect of the surface of SnO2 nanoribbons on their luminescence using x-ray absorption and luminescence spectroscopy</title><title>The Journal of chemical physics</title><addtitle>J Chem Phys</addtitle><description>X-ray excited optical luminescence (XEOL) and x-ray absorption near-edge structure in total electron, x-ray fluorescence, and photoluminescence yields at Sn M5,4-, O K-, and Sn K-edges have been used to study the luminescence from SnO2 nanoribbons. The effect of the surface on the luminescence from SnO2 nanoribbons was studied by preferential excitation of the ions in the near-surface region and at the normal lattice positions, respectively. No noticeable change of luminescence from SnO2 nanoribbons was observed if the Sn ions in the near-surface region were excited selectively, while the luminescence intensity changes markedly when Sn or O ions at the normal lattice positions were excited across the corresponding edges. Based on the experimental results, we show that the luminescence from SnO2 nanoribbons is dominated by energy transfer from the excitation of the whole SnO2 lattice to the surface states. Surface site specificity is not observable due to its low concentration and weak absorption coefficient although the surface plays an important role in the emission as a luminescence center. The energy transfer and site specificity of the XEOL or the lack of the site specificity from a single-phase sample is discussed.</description><subject>ABSORPTION</subject><subject>EMISSION</subject><subject>ENERGY TRANSFER</subject><subject>EXCITATION</subject><subject>FLUORESCENCE</subject><subject>IONS</subject><subject>LUMINESCENCE</subject><subject>MATERIALS</subject><subject>MATERIALS SCIENCE</subject><subject>NANOSTRUCTURES</subject><subject>PHOTOLUMINESCENCE</subject><subject>SEMICONDUCTOR MATERIALS</subject><subject>SPECIFICITY</subject><subject>SPECTROSCOPY</subject><subject>SURFACES</subject><subject>TIN COMPOUNDS</subject><subject>X-RAY SPECTRA</subject><subject>X-RAY SPECTROSCOPY</subject><subject>YIELDS</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNpV0U1LxDAQBuAgirt-HPwDUjwIHrpO0jRtjrL4BQt7cD2XNE3cSJvUpIXdf2-WLYinMPDwzmQGoRsMCwwse8QLUlJMMT9BcwwlTwvG4RTNAQhOOQM2QxchfAMALgg9RzMcOaGsmKPdZqsSpbWSQ-J0MsQqjF4LqQ7lh12TxArrvKlrZ0Pi7IEYn7RjZ6wKUtkox2DsV7JLvdgnog7O94OJUtjmvwt9bONdkK7fX6EzLdqgrqf3En2-PG-Wb-lq_fq-fFqlklAY0jJXjaBa5I0mnBFW61IVlGRa1JBDkQHmTDSN5g2VFEPOCyBZ3IUQOm94ibNLdHfMdWEwVZBmUHIrnbVxlAoDsDxnEd0fUe_dz6jCUHUmzty2wio3horxGI1LEuHDEcr4jeCVrnpvOuH3Mao63KLC1XSLaG-n0LHuVPMnp-Vnv0fMhEI</recordid><startdate>20080414</startdate><enddate>20080414</enddate><creator>Zhou, X T</creator><creator>Zhou, J G</creator><creator>Murphy, M W</creator><creator>Ko, J Y P</creator><creator>Heigl, F</creator><creator>Regier, T</creator><creator>Blyth, R I R</creator><creator>Sham, T K</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>20080414</creationdate><title>The effect of the surface of SnO2 nanoribbons on their luminescence using x-ray absorption and luminescence spectroscopy</title><author>Zhou, X T ; Zhou, J G ; Murphy, M W ; Ko, J Y P ; Heigl, F ; Regier, T ; Blyth, R I R ; Sham, T K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c240t-85eda4fa5df29626bf8e7423fab050730196addf9d4c410597023414aaf5d9813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>ABSORPTION</topic><topic>EMISSION</topic><topic>ENERGY TRANSFER</topic><topic>EXCITATION</topic><topic>FLUORESCENCE</topic><topic>IONS</topic><topic>LUMINESCENCE</topic><topic>MATERIALS</topic><topic>MATERIALS SCIENCE</topic><topic>NANOSTRUCTURES</topic><topic>PHOTOLUMINESCENCE</topic><topic>SEMICONDUCTOR MATERIALS</topic><topic>SPECIFICITY</topic><topic>SPECTROSCOPY</topic><topic>SURFACES</topic><topic>TIN COMPOUNDS</topic><topic>X-RAY SPECTRA</topic><topic>X-RAY SPECTROSCOPY</topic><topic>YIELDS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, X T</creatorcontrib><creatorcontrib>Zhou, J G</creatorcontrib><creatorcontrib>Murphy, M W</creatorcontrib><creatorcontrib>Ko, J Y P</creatorcontrib><creatorcontrib>Heigl, F</creatorcontrib><creatorcontrib>Regier, T</creatorcontrib><creatorcontrib>Blyth, R I R</creatorcontrib><creatorcontrib>Sham, T K</creatorcontrib><creatorcontrib>Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, X T</au><au>Zhou, J G</au><au>Murphy, M W</au><au>Ko, J Y P</au><au>Heigl, F</au><au>Regier, T</au><au>Blyth, R I R</au><au>Sham, T K</au><aucorp>Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of the surface of SnO2 nanoribbons on their luminescence using x-ray absorption and luminescence spectroscopy</atitle><jtitle>The Journal of chemical physics</jtitle><addtitle>J Chem Phys</addtitle><date>2008-04-14</date><risdate>2008</risdate><volume>128</volume><issue>14</issue><spage>144703</spage><epage>144703</epage><pages>144703-144703</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>X-ray excited optical luminescence (XEOL) and x-ray absorption near-edge structure in total electron, x-ray fluorescence, and photoluminescence yields at Sn M5,4-, O K-, and Sn K-edges have been used to study the luminescence from SnO2 nanoribbons. The effect of the surface on the luminescence from SnO2 nanoribbons was studied by preferential excitation of the ions in the near-surface region and at the normal lattice positions, respectively. No noticeable change of luminescence from SnO2 nanoribbons was observed if the Sn ions in the near-surface region were excited selectively, while the luminescence intensity changes markedly when Sn or O ions at the normal lattice positions were excited across the corresponding edges. Based on the experimental results, we show that the luminescence from SnO2 nanoribbons is dominated by energy transfer from the excitation of the whole SnO2 lattice to the surface states. Surface site specificity is not observable due to its low concentration and weak absorption coefficient although the surface plays an important role in the emission as a luminescence center. The energy transfer and site specificity of the XEOL or the lack of the site specificity from a single-phase sample is discussed.</abstract><cop>United States</cop><pmid>18412467</pmid><doi>10.1063/1.2841419</doi><tpages>1</tpages></addata></record> |
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subjects | ABSORPTION EMISSION ENERGY TRANSFER EXCITATION FLUORESCENCE IONS LUMINESCENCE MATERIALS MATERIALS SCIENCE NANOSTRUCTURES PHOTOLUMINESCENCE SEMICONDUCTOR MATERIALS SPECIFICITY SPECTROSCOPY SURFACES TIN COMPOUNDS X-RAY SPECTRA X-RAY SPECTROSCOPY YIELDS |
title | The effect of the surface of SnO2 nanoribbons on their luminescence using x-ray absorption and luminescence spectroscopy |
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