Selective Bifunctional Modification of a Non-catenated Metal−Organic Framework Material via “Click” Chemistry

A noncatenated, Zn-based metal−organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using “click” chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were “clicked” onto the MOF crystals, result...

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Veröffentlicht in:	Journal of the American Chemical Society 2009-09, Vol.131 (38), p.13613-13615
Hauptverfasser:	Gadzikwa, Tendai, Farha, Omar K, Malliakas, Christos D, Kanatzidis, Mercouri G, Hupp, Joseph T, Nguyen, SonBinh T
Format:	Artikel
Sprache:	eng
Schlagworte:	ALKYNES AZIDES BEARINGS CHEMISTRY INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MODIFICATIONS POROUS MATERIALS
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container_title	Journal of the American Chemical Society
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creator	Gadzikwa, Tendai Farha, Omar K Malliakas, Christos D Kanatzidis, Mercouri G Hupp, Joseph T Nguyen, SonBinh T
description	A noncatenated, Zn-based metal−organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using “click” chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were “clicked” onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.
doi_str_mv	10.1021/ja904189d
format	Article
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title	Selective Bifunctional Modification of a Non-catenated Metal−Organic Framework Material via “Click” Chemistry
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