The mechanism of oxidation of 3-mercaptopropionic acid

The mechanism of the oxidation of 3-mercaptopropionic acid (3-MPA) by hydrogen peroxide was studied in the acidic pH range. The nucleophilic attack by sulphur on the peroxide bond controls the rate. Extrapolation of the pH dependency suggests that the rate of attack by the deprotonated dianion is hi...

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Veröffentlicht in:	Canadian journal of chemistry 1997-01, Vol.75 (1), p.9-13
Hauptverfasser:	Forlano, Paula, Olabe, José A, Magallanes, Jorge F, Blesa, Miguel A
Format:	Artikel
Sprache:	eng
Schlagworte:	Electrochemistry Kinetics Oxidation
Online-Zugang:	Volltext
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