Synthetic application of α-hydroxydiazene systems. II. Uncatalyzed and phenol catalyzed radical chain hydro-tert-butylation of unsaturated compounds with tert-butylazodiphenylcarbinol
tert-Butylazodiphenylcarbinol 1 decomposes in benzene solution by a chain mechanism involving tert-butyl radicals. Many olefinic compounds and azobenzene act as radical traps and are hydro-tert-butylated by 1 . The regiochemistry of hydro-tert-butylation of unsymmetric alkenes is that expected for a...
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| Veröffentlicht in: | Canadian journal of chemistry 1976-05, Vol.54 (9), p.1345-1348 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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