attempted synthesis of 4,5-bis(dimethylamino)-1,2,3-thiadiazole

Oxidation of 2-hydrazono-N,N,N′,N′ tetramethylthiooxamide ( 8 ) by various reagents did not provide the expected thiadiazole 4 , but rather gave azines 11 and 12 . It is postulated that the hydrazone derived from 8 lost nitrogen to give carbene 14 which in turn produced 11 and 12 .

Bibliographische Detailangaben

Veröffentlicht in:	Canadian journal of chemistry 1971-09, Vol.49 (17), p.2898-2902
Hauptverfasser:	Oliver, J.E, Stokes, J.B
Format:	Artikel
Sprache:	eng
Schlagworte:	Musca domestica sterilizing
Online-Zugang:	Volltext
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