Enantiomeric 3-hydroxypent-4-enethionamides from thioglucosides of Crambe and Brassica seeds by action of ferrous salts

epi-Progoitrin, the major thioglucoside of Crambe abyssinica seed, is cleaved by ferrous salts to yield (S)-1-cyano-2-hydroxy-3-butene and (S)-3-hydroxypent-4-enethionamide. The products are the same whether obtained from the purified thioglucoside or from the seed meal. Identical behavior was obser...

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Veröffentlicht in:Canadian journal of chemistry 1968-05, Vol.46 (9), p.1507-1512
Hauptverfasser: Austin, F. L, Gent, C. A, Wolff, I. A
Format: Artikel
Sprache:eng
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