Organo(organooxo)mercury(II) chemistry Synthesis and structure of methyl(phenoxo)mercury(II)
Methyl(phenoxo)mercury(II) may be obtained from the reaction of methyl(chloro)mercury(II) with silver(I) oxide, followed by addition of phenol. The dominant motif of the structure is a pair of independent MeHgOPh aggregates (HgC,O 2.05(2) Å, 2.06(1) Å (x2); C-Hg-O 176.6(5)°, 176.3(5)°) loosely asso...
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| Veröffentlicht in: | Canadian journal of chemistry 2006-02, Vol.84 (2), p.77-80 |
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| container_title | Canadian journal of chemistry |
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| creator | Canty, Allan J Devereux, Janette W Skelton, Brian W White, Allan H |
| description | Methyl(phenoxo)mercury(II) may be obtained from the reaction of methyl(chloro)mercury(II) with silver(I) oxide, followed by addition of phenol. The dominant motif of the structure is a pair of independent MeHgOPh aggregates (HgC,O 2.05(2) Å, 2.06(1) Å (x2); C-Hg-O 176.6(5)°, 176.3(5)°) loosely associated about a quasi-inversion centre by Hg···O interactions (2.702(9) Å, 2.719(9) Å) to form a dimer (Hg-O-Hg′ 106.0(4)°, 106.5(4)°; O-Hg-O′ 73.0(3)°, 72.6(3)°), the dimer stacking up the short crystallographic c axis (= 6.914(1) Å) at spacings c/2. Vibrational spectroscopic studies are insensitive to the associative interactions.
Key words: mercury, methylmercury, organomercury, structure, aryloxide, phenoxide. |
| doi_str_mv | 10.1139/v05-219 |
| format | Article |
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Key words: mercury, methylmercury, organomercury, structure, aryloxide, phenoxide.</abstract><cop>Ottawa, Canada</cop><pub>NRC Research Press</pub><doi>10.1139/v05-219</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| title | Organo(organooxo)mercury(II) chemistry Synthesis and structure of methyl(phenoxo)mercury(II) |
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