Improved simple synthesis of cyclic sulfates from trimethylsilyl chlorosulfonate

Reaction of iodosobenzene and trimethylsilyl chlorosulfonate followed by removal of the solvent and trimethylchlorosilane gives phenyliodosulfate. This can be used without further purification to prepare cyclic sulfates from alkenes, including vinylsilanes. Previous results have shown that if the tr...

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Veröffentlicht in:	Canadian journal of chemistry 2000-11, Vol.78 (11), p.1479-1483
Hauptverfasser:	Bassindale, Alan R, Katampe, Ibrahim, Taylor, Peter G
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Chemical bonds Chemistry Chlorine Organometallic compounds Silicon Silicon compounds Sulfates Sulfur Sulphur compounds
Online-Zugang:	Volltext
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