Does Twisted π-Conjugation Framework Always Induce Efficient Intersystem Crossing? A Case Study with Benzo[b]- and [a]Phenanthrene-Fused BODIPY Derivatives and Identification of a Dark State

The photophysical properties, especially the intersystem crossing (ISC) of two heavy-atom-free BODIPY derivatives with twisted π-conjugated frameworks (benzo[b]-fused BODIPY, BDP-B; and [a]phenanthrene-fused BODIPY, BDP-P), are studied with steady-state and time-resolved optical and electron paramag...

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Veröffentlicht in:	JOURNAL OF PHYSICAL CHEMISTRY B 2021-06, Vol.125 (23), p.6280-6295
Hauptverfasser:	Yan, Yuxin, Sukhanov, Andrei A, Bousquet, Manon H.E, Guan, Qinglin, Zhao, Jianzhang, Voronkova, Violeta K, Escudero, Daniel, Barbon, Antonio, Xing, Yongheng, Gurzadyan, Gagik G, Jacquemin, Denis
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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