Highly Selective Removal of Perfluorinated Contaminants by Adsorption on All-Silica Zeolite Beta
Perfluorinated alkylated substances (PFASs) are widely used in industrial and commercial applications, leading to a widespread occurrence of these persistent and harmful contaminants in our environment. Removal of these compounds from surface and waste waters is being mandated by European and U.S. g...
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| Veröffentlicht in: | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 2020-08, Vol.59 (33), p.14086-14090 |
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| container_title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION |
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| creator | Van den Bergh, Matthias Krajnc, Andraz Voorspoels, Stefan Tavares, Sergio Rodrigues Mullens, Steven Beurroies, Isabelle Maurin, Guillaume Mali, Gregor De Vos, Dirk E |
| description | Perfluorinated alkylated substances (PFASs) are widely used in industrial and commercial applications, leading to a widespread occurrence of these persistent and harmful contaminants in our environment. Removal of these compounds from surface and waste waters is being mandated by European and U.S. governments. Currently, there are no treatment techniques available that lower the concentrations of these compounds for large water bodies in a cost- and energy-efficient way. We hereby propose a hydrophobic, all-silica zeolite Beta material that is a highly selective and high-capacity adsorbent for PFASs, even in the presence of organic competitors. Advanced characterization data demonstrate that the adsorption process is driven by a very negative adsorption enthalpy and favorable steric factors. |
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| ispartof | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020-08, Vol.59 (33), p.14086-14090 |
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| source | Lirias (KU Leuven Association); Access via Wiley Online Library |
| title | Highly Selective Removal of Perfluorinated Contaminants by Adsorption on All-Silica Zeolite Beta |
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