Two-dimensional WS2 nanoribbon deposition by conversion of pre-patterned amorphous silicon

We present a method for area selective deposition of 2D WS2 nanoribbons with tunable thickness on a dielectric substrate. The process is based on a complete conversion of a pre-patterned, H-terminated Si layer to metallic W by WF6, followed by in situ sulfidation by H2S. The reaction process, perfor...

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Veröffentlicht in:Nanotechnology 2017, Vol.28 (4)
Hauptverfasser: Heyne, Markus, de Marneffe, Jean-Francois, Delabie, Annelies, Caymax, Matty, Neyts, Erik C, Radu, Iuliana, Huyghebaert, Cedric, De Gendt, Stefan
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container_issue 4
container_start_page
container_title Nanotechnology
container_volume 28
creator Heyne, Markus
de Marneffe, Jean-Francois
Delabie, Annelies
Caymax, Matty
Neyts, Erik C
Radu, Iuliana
Huyghebaert, Cedric
De Gendt, Stefan
description We present a method for area selective deposition of 2D WS2 nanoribbons with tunable thickness on a dielectric substrate. The process is based on a complete conversion of a pre-patterned, H-terminated Si layer to metallic W by WF6, followed by in situ sulfidation by H2S. The reaction process, performed at 450 °C, yields nanoribbons with lateral dimension down to 20 nm and with random basal plane orientation. The thickness of the nanoribbons is accurately controlled by the thickness of the pre-deposited Si layer. Upon rapid thermal annealing at 900 °C under inert gas, the WS2 basal planes align parallel to the substrate.
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title Two-dimensional WS2 nanoribbon deposition by conversion of pre-patterned amorphous silicon
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