Dichlorido{2-[(2,6-diethylphenyl)iminomethyl]quinoline-κ2N,N}palladium(II) acetonitrile monosolvate

Dichlorido{2-[(2,6-diethylphenyl)iminomethyl]quinoline-κ2N,N}palladium(II) acetonitrile monosolvate

The title complex, [PdCl(2)(C(20)H(20)N(2))]·CH(3)CN, was synthesized by the reaction of 2-[(2,6-diethylphenyl)iminomethyl]quinoline with dichlorido(cycloocta-1,5-diene)palladium(II) in dry CH(2)Cl(2). The Pd(II) ion is coordinated by two N atoms of the bidentate quinoline ligand and by two chloride...

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Veröffentlicht in:Acta Crystallographica C, Crystal Structure Communications Crystal Structure Communications, 2012, Vol.68 (Pt 12), p.356-358
Hauptverfasser: Motswainyana, William M, Onani, Martin O, Jacobs, Jeroen, Van Meervelt, Luc
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container_end_page 358
container_issue Pt 12
container_start_page 356
container_title Acta Crystallographica C, Crystal Structure Communications
container_volume 68
creator Motswainyana, William M
Onani, Martin O
Jacobs, Jeroen
Van Meervelt, Luc
description The title complex, [PdCl(2)(C(20)H(20)N(2))]·CH(3)CN, was synthesized by the reaction of 2-[(2,6-diethylphenyl)iminomethyl]quinoline with dichlorido(cycloocta-1,5-diene)palladium(II) in dry CH(2)Cl(2). The Pd(II) ion is coordinated by two N atoms of the bidentate quinoline ligand and by two chloride anions, generating a distorted square-planar coordination geometry around the metal centre. There is a detectable trans influence for the chloride ligands. The crystal packing is characterized by π-π stacking between the quinoline rings. The use of acetonitrile as the crystallization solvent was essential for obtaining good-quality crystals.
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title Dichlorido{2-[(2,6-diethylphenyl)iminomethyl]quinoline-κ2N,N}palladium(II) acetonitrile monosolvate
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