Bubble-Point Measurement of Binary Mixture for the CO 2 + Caprolactone Acrylate System in High Pressure

Experimental data of phase equilibrium is reported for caprolactone acrylate in supercritical carbon dioxide. Bubble-point data was measured by synthetic method at temperatures ranging from (313.2 to 393.2) K and pressures up to 55.93 MPa. In this research, the solubility of carbon dioxide for the (...

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Veröffentlicht in:Korean chemical engineering research 2019-12, Vol.57 (6), p.826-831
Hauptverfasser: Jeong, Jong-Dae, Byun, Hun-Soo
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description Experimental data of phase equilibrium is reported for caprolactone acrylate in supercritical carbon dioxide. Bubble-point data was measured by synthetic method at temperatures ranging from (313.2 to 393.2) K and pressures up to 55.93 MPa. In this research, the solubility of carbon dioxide for the (carbon dioxide + caprolactone acrylate) system decreases as temperature increases at a constant pressure. The (carbon dioxide + caprolactone acrylate) system exhibits type-I phase behavior. The experimental result for the (carbon dioxide + caprolactone acrylate) system was correlated with Peng-Robinson equation of state using mixing rule. The critical property of caprolactone acrylate was predicted with the Joback and Lyderson method.
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subjects Bubble-point
Caprolactone acrylate
Carbon dioxide
Phase behavior
Pressure-composition
title Bubble-Point Measurement of Binary Mixture for the CO 2 + Caprolactone Acrylate System in High Pressure
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