Diels-Alder Cycloaddition of Cyclopentadiene with Ethylacrylate Catalyzed by Mesoporous Al-MCM-48 and Al-MCM-41 Catalysts
In the present work, Diels-Alder reaction of cyclopentadiene with ethylacrylate has been carried out by using two types of mesoporous solid acid catalysts (Al-MCM-41, Al-MCM-48) with different pore structures. The specific topology of Al-MCM-48 (cubic Ia3d structure composed of two independent 3-D c...
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| Veröffentlicht in: | Bulletin of the Korean Chemical Society 2008, Vol.29 (10), p.1993-1997 |
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| container_end_page | 1997 |
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| container_issue | 10 |
| container_start_page | 1993 |
| container_title | Bulletin of the Korean Chemical Society |
| container_volume | 29 |
| creator | Shon, Jeong-Kuk Sim, Jae-Yi Thakur, Santosh Singh Ko, Eun-Mi Kong, Soo-Sung Choi, Ji-Yun Kang, Min Senapati, Bidyut Kumar Choi, Doo-Seoung Ryu, Do-Hyun Kim, Ji-Man |
| description | In the present work, Diels-Alder reaction of cyclopentadiene with ethylacrylate has been carried out by using two types of mesoporous solid acid catalysts (Al-MCM-41, Al-MCM-48) with different pore structures. The specific topology of Al-MCM-48 (cubic Ia3d structure composed of two independent 3-D channel systems) exhibit higher activity and stereo-control than those of Al-MCM-41 (hexagonal packing of 1-D channels). The physical properties of Al-MCM-48 catalyst, such as high accessibility of reactants to the acid sites, spatial confinement in the nanoscopic reactors, and 3-D channel network structure that are effective adsorption and diffusion of reactants, play a crucial role in the present study. |
| format | Article |
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| issn | 0253-2964 1229-5949 |
| language | kor |
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| source | EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| title | Diels-Alder Cycloaddition of Cyclopentadiene with Ethylacrylate Catalyzed by Mesoporous Al-MCM-48 and Al-MCM-41 Catalysts |
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