철-디피리딜-메페남산 삼원착물을 이용한 메페남산의 정량
A PVC membrane electrodes based on Fe(II)-dipyridyl-mefenamic acid ternary complex as ion exchanger were prepared using o-nitrophenyl octyl ether as a plasticizer. The 2,2'-dipyridyl, 4,4'-dipyridyl and 4,4'-dipyridyl-2,2'-dipyridyl were used as dipyridyl derivative ligand. The e...
Gespeichert in:
| Veröffentlicht in: | Punsŏk kwahak 2001, Vol.14 (1), p.59-63 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | kor |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 63 |
|---|---|
| container_issue | 1 |
| container_start_page | 59 |
| container_title | Punsŏk kwahak |
| container_volume | 14 |
| creator | 남수자 문현숙 이미나 정문모 허문희 안문규 Nam, Su Ja Moon, Hyun Sook Lee, Mi Na Jung, Moon Mo Hur, Moon Hye Ahn, Moon Kyu |
| description | A PVC membrane electrodes based on Fe(II)-dipyridyl-mefenamic acid ternary complex as ion exchanger were prepared using o-nitrophenyl octyl ether as a plasticizer. The 2,2'-dipyridyl, 4,4'-dipyridyl and 4,4'-dipyridyl-2,2'-dipyridyl were used as dipyridyl derivative ligand. The electrode dxhibits a fast stable and linear response for $10^{-5}-10^{-3}mol/L$ mefenamate with an anionic slope of -55.98, -49.47, -59.35mV/decade in pH 8.9 borate buffer solution respectively. Potentiometric selectivity measurements revealed negligible interferences from aromatic and aliphatic carboxylic acid salts. 철-디피리딜-메페남산 삼원착물을 이온교환체로, NPOE(o-nitrophenyl octyl ether)를 가소게, PVC[poly(vinyl chloride)]를 지지체로 사용한 메페남산 이온선택성막 전극을 제작하였다. 디피리딜 화합물은 2,2'-디피리딜, 4,4'-디피리딜 그리고 4,4'-디페닐-2,2'-디피리딜을 이용하였다. 이들 막전극은 pH 8.9의 붕산완충액 중에서 $10^{-5}{\sim}10^{-3}mol/L$ 농도의 메페남산에 대하여 감응전위가 -55.98, -49.47 그리고 -59.35mV/decade를 각각 나타내는 직선성이었다. 방향족 및 지방족 카복실산염의 존재는 전극의 감응에 지장을 주지 않았다. |
| format | Article |
| fullrecord | <record><control><sourceid>kisti</sourceid><recordid>TN_cdi_kisti_ndsl_JAKO200119068855181</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>JAKO200119068855181</sourcerecordid><originalsourceid>FETCH-LOGICAL-k522-4c9e8b0f1efaf819a8cd90bcd086ac56003918f9e4f499640d955c78e066167e3</originalsourceid><addsrcrecordid>eNpNjD9LAzEcQDMoWGq_wy2OgV9ySS4ZS_F_sUv3cs0lUFtc4ic4XFzEIYWiPewkHnQo4njfKLnv0IIOvuUtj3eEOoRSjoGI9AT1nLuHA5xlqRIddBe_Nzh43_omfG6DX-NQ-_ZlFcqvWO6SWDbx_TXu6rBtYvWUxOonvtXtcp38z2K1SuJmGT6eT9GxzRfO9P7cReOL8_HgCg9Hl9eD_hDPOaWYaWXkFCwxNreSqFzqQsFUFyBFrrkASBWRVhlmmVKCQaE415k0IAQRmUm76Ox3O5-5x9nkoXCLyU3_dkQBCFEgpOScSJLuAS77X9s</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>철-디피리딜-메페남산 삼원착물을 이용한 메페남산의 정량</title><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><creator>남수자 ; 문현숙 ; 이미나 ; 정문모 ; 허문희 ; 안문규 ; Nam, Su Ja ; Moon, Hyun Sook ; Lee, Mi Na ; Jung, Moon Mo ; Hur, Moon Hye ; Ahn, Moon Kyu</creator><creatorcontrib>남수자 ; 문현숙 ; 이미나 ; 정문모 ; 허문희 ; 안문규 ; Nam, Su Ja ; Moon, Hyun Sook ; Lee, Mi Na ; Jung, Moon Mo ; Hur, Moon Hye ; Ahn, Moon Kyu</creatorcontrib><description>A PVC membrane electrodes based on Fe(II)-dipyridyl-mefenamic acid ternary complex as ion exchanger were prepared using o-nitrophenyl octyl ether as a plasticizer. The 2,2'-dipyridyl, 4,4'-dipyridyl and 4,4'-dipyridyl-2,2'-dipyridyl were used as dipyridyl derivative ligand. The electrode dxhibits a fast stable and linear response for $10^{-5}-10^{-3}mol/L$ mefenamate with an anionic slope of -55.98, -49.47, -59.35mV/decade in pH 8.9 borate buffer solution respectively. Potentiometric selectivity measurements revealed negligible interferences from aromatic and aliphatic carboxylic acid salts. 철-디피리딜-메페남산 삼원착물을 이온교환체로, NPOE(o-nitrophenyl octyl ether)를 가소게, PVC[poly(vinyl chloride)]를 지지체로 사용한 메페남산 이온선택성막 전극을 제작하였다. 디피리딜 화합물은 2,2'-디피리딜, 4,4'-디피리딜 그리고 4,4'-디페닐-2,2'-디피리딜을 이용하였다. 이들 막전극은 pH 8.9의 붕산완충액 중에서 $10^{-5}{\sim}10^{-3}mol/L$ 농도의 메페남산에 대하여 감응전위가 -55.98, -49.47 그리고 -59.35mV/decade를 각각 나타내는 직선성이었다. 방향족 및 지방족 카복실산염의 존재는 전극의 감응에 지장을 주지 않았다.</description><identifier>ISSN: 1225-0163</identifier><language>kor</language><ispartof>Punsŏk kwahak, 2001, Vol.14 (1), p.59-63</ispartof><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,4009</link.rule.ids></links><search><creatorcontrib>남수자</creatorcontrib><creatorcontrib>문현숙</creatorcontrib><creatorcontrib>이미나</creatorcontrib><creatorcontrib>정문모</creatorcontrib><creatorcontrib>허문희</creatorcontrib><creatorcontrib>안문규</creatorcontrib><creatorcontrib>Nam, Su Ja</creatorcontrib><creatorcontrib>Moon, Hyun Sook</creatorcontrib><creatorcontrib>Lee, Mi Na</creatorcontrib><creatorcontrib>Jung, Moon Mo</creatorcontrib><creatorcontrib>Hur, Moon Hye</creatorcontrib><creatorcontrib>Ahn, Moon Kyu</creatorcontrib><title>철-디피리딜-메페남산 삼원착물을 이용한 메페남산의 정량</title><title>Punsŏk kwahak</title><addtitle>Analytical science & technology</addtitle><description>A PVC membrane electrodes based on Fe(II)-dipyridyl-mefenamic acid ternary complex as ion exchanger were prepared using o-nitrophenyl octyl ether as a plasticizer. The 2,2'-dipyridyl, 4,4'-dipyridyl and 4,4'-dipyridyl-2,2'-dipyridyl were used as dipyridyl derivative ligand. The electrode dxhibits a fast stable and linear response for $10^{-5}-10^{-3}mol/L$ mefenamate with an anionic slope of -55.98, -49.47, -59.35mV/decade in pH 8.9 borate buffer solution respectively. Potentiometric selectivity measurements revealed negligible interferences from aromatic and aliphatic carboxylic acid salts. 철-디피리딜-메페남산 삼원착물을 이온교환체로, NPOE(o-nitrophenyl octyl ether)를 가소게, PVC[poly(vinyl chloride)]를 지지체로 사용한 메페남산 이온선택성막 전극을 제작하였다. 디피리딜 화합물은 2,2'-디피리딜, 4,4'-디피리딜 그리고 4,4'-디페닐-2,2'-디피리딜을 이용하였다. 이들 막전극은 pH 8.9의 붕산완충액 중에서 $10^{-5}{\sim}10^{-3}mol/L$ 농도의 메페남산에 대하여 감응전위가 -55.98, -49.47 그리고 -59.35mV/decade를 각각 나타내는 직선성이었다. 방향족 및 지방족 카복실산염의 존재는 전극의 감응에 지장을 주지 않았다.</description><issn>1225-0163</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><sourceid>JDI</sourceid><recordid>eNpNjD9LAzEcQDMoWGq_wy2OgV9ySS4ZS_F_sUv3cs0lUFtc4ic4XFzEIYWiPewkHnQo4njfKLnv0IIOvuUtj3eEOoRSjoGI9AT1nLuHA5xlqRIddBe_Nzh43_omfG6DX-NQ-_ZlFcqvWO6SWDbx_TXu6rBtYvWUxOonvtXtcp38z2K1SuJmGT6eT9GxzRfO9P7cReOL8_HgCg9Hl9eD_hDPOaWYaWXkFCwxNreSqFzqQsFUFyBFrrkASBWRVhlmmVKCQaE415k0IAQRmUm76Ox3O5-5x9nkoXCLyU3_dkQBCFEgpOScSJLuAS77X9s</recordid><startdate>2001</startdate><enddate>2001</enddate><creator>남수자</creator><creator>문현숙</creator><creator>이미나</creator><creator>정문모</creator><creator>허문희</creator><creator>안문규</creator><creator>Nam, Su Ja</creator><creator>Moon, Hyun Sook</creator><creator>Lee, Mi Na</creator><creator>Jung, Moon Mo</creator><creator>Hur, Moon Hye</creator><creator>Ahn, Moon Kyu</creator><scope>JDI</scope></search><sort><creationdate>2001</creationdate><title>철-디피리딜-메페남산 삼원착물을 이용한 메페남산의 정량</title><author>남수자 ; 문현숙 ; 이미나 ; 정문모 ; 허문희 ; 안문규 ; Nam, Su Ja ; Moon, Hyun Sook ; Lee, Mi Na ; Jung, Moon Mo ; Hur, Moon Hye ; Ahn, Moon Kyu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-k522-4c9e8b0f1efaf819a8cd90bcd086ac56003918f9e4f499640d955c78e066167e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>kor</language><creationdate>2001</creationdate><toplevel>online_resources</toplevel><creatorcontrib>남수자</creatorcontrib><creatorcontrib>문현숙</creatorcontrib><creatorcontrib>이미나</creatorcontrib><creatorcontrib>정문모</creatorcontrib><creatorcontrib>허문희</creatorcontrib><creatorcontrib>안문규</creatorcontrib><creatorcontrib>Nam, Su Ja</creatorcontrib><creatorcontrib>Moon, Hyun Sook</creatorcontrib><creatorcontrib>Lee, Mi Na</creatorcontrib><creatorcontrib>Jung, Moon Mo</creatorcontrib><creatorcontrib>Hur, Moon Hye</creatorcontrib><creatorcontrib>Ahn, Moon Kyu</creatorcontrib><collection>KoreaScience</collection><jtitle>Punsŏk kwahak</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>남수자</au><au>문현숙</au><au>이미나</au><au>정문모</au><au>허문희</au><au>안문규</au><au>Nam, Su Ja</au><au>Moon, Hyun Sook</au><au>Lee, Mi Na</au><au>Jung, Moon Mo</au><au>Hur, Moon Hye</au><au>Ahn, Moon Kyu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>철-디피리딜-메페남산 삼원착물을 이용한 메페남산의 정량</atitle><jtitle>Punsŏk kwahak</jtitle><addtitle>Analytical science & technology</addtitle><date>2001</date><risdate>2001</risdate><volume>14</volume><issue>1</issue><spage>59</spage><epage>63</epage><pages>59-63</pages><issn>1225-0163</issn><abstract>A PVC membrane electrodes based on Fe(II)-dipyridyl-mefenamic acid ternary complex as ion exchanger were prepared using o-nitrophenyl octyl ether as a plasticizer. The 2,2'-dipyridyl, 4,4'-dipyridyl and 4,4'-dipyridyl-2,2'-dipyridyl were used as dipyridyl derivative ligand. The electrode dxhibits a fast stable and linear response for $10^{-5}-10^{-3}mol/L$ mefenamate with an anionic slope of -55.98, -49.47, -59.35mV/decade in pH 8.9 borate buffer solution respectively. Potentiometric selectivity measurements revealed negligible interferences from aromatic and aliphatic carboxylic acid salts. 철-디피리딜-메페남산 삼원착물을 이온교환체로, NPOE(o-nitrophenyl octyl ether)를 가소게, PVC[poly(vinyl chloride)]를 지지체로 사용한 메페남산 이온선택성막 전극을 제작하였다. 디피리딜 화합물은 2,2'-디피리딜, 4,4'-디피리딜 그리고 4,4'-디페닐-2,2'-디피리딜을 이용하였다. 이들 막전극은 pH 8.9의 붕산완충액 중에서 $10^{-5}{\sim}10^{-3}mol/L$ 농도의 메페남산에 대하여 감응전위가 -55.98, -49.47 그리고 -59.35mV/decade를 각각 나타내는 직선성이었다. 방향족 및 지방족 카복실산염의 존재는 전극의 감응에 지장을 주지 않았다.</abstract><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1225-0163 |
| ispartof | Punsŏk kwahak, 2001, Vol.14 (1), p.59-63 |
| issn | 1225-0163 |
| language | kor |
| recordid | cdi_kisti_ndsl_JAKO200119068855181 |
| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
| title | 철-디피리딜-메페남산 삼원착물을 이용한 메페남산의 정량 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-24T00%3A37%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-kisti&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=%EC%B2%A0-%EB%94%94%ED%94%BC%EB%A6%AC%EB%94%9C-%EB%A9%94%ED%8E%98%EB%82%A8%EC%82%B0%20%EC%82%BC%EC%9B%90%EC%B0%A9%EB%AC%BC%EC%9D%84%20%EC%9D%B4%EC%9A%A9%ED%95%9C%20%EB%A9%94%ED%8E%98%EB%82%A8%EC%82%B0%EC%9D%98%20%EC%A0%95%EB%9F%89&rft.jtitle=Puns%C5%8Fk%20kwahak&rft.au=%EB%82%A8%EC%88%98%EC%9E%90&rft.date=2001&rft.volume=14&rft.issue=1&rft.spage=59&rft.epage=63&rft.pages=59-63&rft.issn=1225-0163&rft_id=info:doi/&rft_dat=%3Ckisti%3EJAKO200119068855181%3C/kisti%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |