A Novel Iron(III) Complex with a Tridentate Ligand as a Functional Model for Catechol Dioxygenases: Properties and Reactivity of [Fe(BBA)DBC]$ClO_4

[FeIII(BBA)DBC]ClO4 as a new functional model for catechol dioxygenases has been synthesized, where BBA is a bis(benzimidazolyl-2-methyl)amine and DBC is a 3,5-di-tert-butylcatecholate dianion.The BBA complex has a structuralfeature that iron cent er has a five-coordinate geometry similar to that of...

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Veröffentlicht in:Bulletin of the Korean Chemical Society 2000, Vol.21 (9), p.923-928
Hauptverfasser: 윤성호, 이호진, 이강봉, Yun, Seong Ho, Lee, Ho Jin, Lee, Gang Bong
Format: Artikel
Sprache:kor
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