Photoaddition Reaction of 5,7-Dimethoxycoumarin with Adenosine
The photoreaction of 5,7-dimethoxycoumarin with adenosine has been carried out in a dry film state. The mixture of DMC and adenosine was irradiated with 350 nm UV light and two major products were isolated. The structure was determined by various spectroscopic measurements involving $^{13}C$ nuclear...
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| Veröffentlicht in: | Bulletin of the Korean Chemical Society 1987, Vol.8 (3), p.206-211 |
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| container_title | Bulletin of the Korean Chemical Society |
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| creator | Cho, Tae-Heung Shim, Hyun-Kwan Shim, Sang-Chul |
| description | The photoreaction of 5,7-dimethoxycoumarin with adenosine has been carried out in a dry film state. The mixture of DMC and adenosine was irradiated with 350 nm UV light and two major products were isolated. The structure was determined by various spectroscopic measurements involving $^{13}C$ nuclear magnetic resonance and fast atom bombardment mass spectrometry. These addition products were produced by covalent bond formation between the pyrone ring at carbon 3 or 4 and the sugar ring moiety of adenosine at carbon 5'. |
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The mixture of DMC and adenosine was irradiated with 350 nm UV light and two major products were isolated. The structure was determined by various spectroscopic measurements involving $^{13}C$ nuclear magnetic resonance and fast atom bombardment mass spectrometry. 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The mixture of DMC and adenosine was irradiated with 350 nm UV light and two major products were isolated. The structure was determined by various spectroscopic measurements involving $^{13}C$ nuclear magnetic resonance and fast atom bombardment mass spectrometry. 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The mixture of DMC and adenosine was irradiated with 350 nm UV light and two major products were isolated. The structure was determined by various spectroscopic measurements involving $^{13}C$ nuclear magnetic resonance and fast atom bombardment mass spectrometry. These addition products were produced by covalent bond formation between the pyrone ring at carbon 3 or 4 and the sugar ring moiety of adenosine at carbon 5'.</abstract><oa>free_for_read</oa></addata></record> |
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| ispartof | Bulletin of the Korean Chemical Society, 1987, Vol.8 (3), p.206-211 |
| issn | 0253-2964 1229-5949 |
| language | kor |
| recordid | cdi_kisti_ndsl_JAKO198713464451428 |
| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry |
| title | Photoaddition Reaction of 5,7-Dimethoxycoumarin with Adenosine |
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