Ba-Ferrite 의 생성 및 자기적 성질에 미치는 분쇄시간의 영향

The effects of ball-milling time on solid state reactions in the system $BaCO_3-Fe_2O_3$ and the magnetic properties of Ba-ferrite 4(BaFe_{12}O_{19})$ have been studied. $BaCO_3-Fe_2O_3 $mixtures were prepared by ball-milling for varying lengths of time; 5, 15, 30, 80 and 200 hours. Techniques emplo...

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Veröffentlicht in:Journal of the Korean Chemical Society 1983, Vol.27 (3), p.224-232
Hauptverfasser: 남효덕(Hyo Duk Nam), 조상희(Sang Hee Cho)
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creator 남효덕(Hyo Duk Nam)
조상희(Sang Hee Cho)
description The effects of ball-milling time on solid state reactions in the system $BaCO_3-Fe_2O_3$ and the magnetic properties of Ba-ferrite 4(BaFe_{12}O_{19})$ have been studied. $BaCO_3-Fe_2O_3 $mixtures were prepared by ball-milling for varying lengths of time; 5, 15, 30, 80 and 200 hours. Techniques employed were thermogravimetry, X-ray diffraction analysis, scanning electron microscopy and B-H curve tracer. It is shown that the aggregation states and superparamagnetic size fractions obtained by increasing ball-milling time have remarkable effects on solid state reactions and magnetic properties of Ba-ferrite. $Fe_2O_3$와 $BaCO_3$ 분체를 철제 ball-mill로 각각 5, 15, 30, 80, 200시간 혼합분쇄하여 얻어진 $BaCO_3-Fe_2O_3$계에서 고체반응 및 생성 Ba-ferrite의 자기적 성질에 미치는 분쇄시간의 영향을 조사하였다. 열천칭, X-선 회절기, 주사형전자현미경 및 B-H 이력곡선기 등을 사용하여 조사한 결과 일정시간 이상 분쇄시켰을 때 입자의 응집현상과 함께 초상자성을 띄는 미립자가 생기게 되어 Ba-ferrite의 생성 및 자기적 성질에 중요한 영향을 미친다는 사실을 확인했다.
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Techniques employed were thermogravimetry, X-ray diffraction analysis, scanning electron microscopy and B-H curve tracer. 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Techniques employed were thermogravimetry, X-ray diffraction analysis, scanning electron microscopy and B-H curve tracer. 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Techniques employed were thermogravimetry, X-ray diffraction analysis, scanning electron microscopy and B-H curve tracer. It is shown that the aggregation states and superparamagnetic size fractions obtained by increasing ball-milling time have remarkable effects on solid state reactions and magnetic properties of Ba-ferrite. $Fe_2O_3$와 $BaCO_3$ 분체를 철제 ball-mill로 각각 5, 15, 30, 80, 200시간 혼합분쇄하여 얻어진 $BaCO_3-Fe_2O_3$계에서 고체반응 및 생성 Ba-ferrite의 자기적 성질에 미치는 분쇄시간의 영향을 조사하였다. 열천칭, X-선 회절기, 주사형전자현미경 및 B-H 이력곡선기 등을 사용하여 조사한 결과 일정시간 이상 분쇄시켰을 때 입자의 응집현상과 함께 초상자성을 띄는 미립자가 생기게 되어 Ba-ferrite의 생성 및 자기적 성질에 중요한 영향을 미친다는 사실을 확인했다.</abstract><pub>대한화학회</pub><tpages>9</tpages><oa>free_for_read</oa></addata></record>
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