Ethanol-Water 溶液內에서의 p-Nitrobenzyl Chloride의 Solvolysis

The thermodynamic parameters for the solvolysis of the p-nitrobenzyl chloride which take place in the ethanol-water mixture media were determined. From the application of this data to the formula ${\delta}_M{\Delta}H^{\neq} = a'Y + b{\delta}_M{\Delta}S^{\leq}$ the following conclusion was obtained. The substrate constant a' for this reaction was not varied in the media which contain more than 50% alcohol and less than 50% alcohol. From this, it is clear that the mechanism of this reaction is the same both in the water-rich solvent and in the alcohol-rich solvent. Ethanol-water mixture 內에서 일어나는 p-nitrobenzyl chloride의 solvolysis反應에 대한 熱力學的 parameter를 구하고 이 data를 ${\delta}_M{\Delta}H^{\neq} = a'Y + b{\delta}_M{\Delta}S^{\leq}$에 適用함으로써 反應常數 a'가 50% 이하의 alcohol solvent에서나 50% 이상의 solvent에서 같다는 것을 알 수 있었다. 즉 water-rich solvent에서나 alcohol-rich solvent에서나 solvolysis反應의 mechanism은 변함이 없다는 것을 알았다.