A proposal to standardize soil/solution herbicide distribution coefficients

Herbicide soil/solution distribution coefficients (Kd) are used in mathematical models to predict the movement of herbicides in soil and groundwater. Herbicides bind to various soil constituents to differing degrees. The universal soil colloid that binds most herbicides is organic matter (OM), howev...

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Veröffentlicht in:Weed science 2000-01, Vol.48 (1), p.75-88
Hauptverfasser: Weber, Jerome B., Wilkerson, Gail G., Michael Linker, H., Wilcut, John W., Leidy, Ross B., Senseman, Scott, Witt, William W., Barrett, Michael, Vencill, William K., Shaw, David R., Mueller, Thomas C., Miller, Donnie K., Brecke, Barry J., Talbert, Ronald E., Peeper, Thomas F.
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container_end_page 88
container_issue 1
container_start_page 75
container_title Weed science
container_volume 48
creator Weber, Jerome B.
Wilkerson, Gail G.
Michael Linker, H.
Wilcut, John W.
Leidy, Ross B.
Senseman, Scott
Witt, William W.
Barrett, Michael
Vencill, William K.
Shaw, David R.
Mueller, Thomas C.
Miller, Donnie K.
Brecke, Barry J.
Talbert, Ronald E.
Peeper, Thomas F.
description Herbicide soil/solution distribution coefficients (Kd) are used in mathematical models to predict the movement of herbicides in soil and groundwater. Herbicides bind to various soil constituents to differing degrees. The universal soil colloid that binds most herbicides is organic matter (OM), however clay minerals (CM) and metallic hydrous oxides are more retentive for cationic, phosphoric, and arsenic acid compounds. Weakly basic herbicides bind to both organic and inorganic soil colloids. The soil organic carbon (OC) affinity coefficient (Koc) has become a common parameter for comparing herbicide binding in soil; however, because OM and OC determinations vary greatly between methods and laboratories, Koc values may vary greatly. This proposal discusses this issue and offers suggestions for obtaining the most accurate Kd, Freundlich constant (Kf), and Koc values for herbicides listed in the WSSA Herbicide Handbook and Supplement. Nomenclature: Readers are referred to the WSSA Herbicide Handbook and Supplement for the chemical names of the herbicides.
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Herbicides bind to various soil constituents to differing degrees. The universal soil colloid that binds most herbicides is organic matter (OM), however clay minerals (CM) and metallic hydrous oxides are more retentive for cationic, phosphoric, and arsenic acid compounds. Weakly basic herbicides bind to both organic and inorganic soil colloids. The soil organic carbon (OC) affinity coefficient (Koc) has become a common parameter for comparing herbicide binding in soil; however, because OM and OC determinations vary greatly between methods and laboratories, Koc values may vary greatly. This proposal discusses this issue and offers suggestions for obtaining the most accurate Kd, Freundlich constant (Kf), and Koc values for herbicides listed in the WSSA Herbicide Handbook and Supplement. 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subjects Acid soils
Agrology
arsenic
clay minerals
Clay soils
Coefficients
groundwater
herbicide binding
herbicide movement
herbicide retention
herbicide sorption
Herbicides
Koc
leaching potential
mathematical models
organic matter
Organic soils
oxides
soil
Soil biochemistry
soil colloids
soil organic carbon
Soil organic matter
Soil properties
Soil water
SOIL, AIR, AND WATER
weed science
title A proposal to standardize soil/solution herbicide distribution coefficients
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