A proposal to standardize soil/solution herbicide distribution coefficients
Herbicide soil/solution distribution coefficients (Kd) are used in mathematical models to predict the movement of herbicides in soil and groundwater. Herbicides bind to various soil constituents to differing degrees. The universal soil colloid that binds most herbicides is organic matter (OM), howev...
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Veröffentlicht in: | Weed science 2000-01, Vol.48 (1), p.75-88 |
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creator | Weber, Jerome B. Wilkerson, Gail G. Michael Linker, H. Wilcut, John W. Leidy, Ross B. Senseman, Scott Witt, William W. Barrett, Michael Vencill, William K. Shaw, David R. Mueller, Thomas C. Miller, Donnie K. Brecke, Barry J. Talbert, Ronald E. Peeper, Thomas F. |
description | Herbicide soil/solution distribution coefficients (Kd) are used in mathematical models to predict the movement of herbicides in soil and groundwater. Herbicides bind to various soil constituents to differing degrees. The universal soil colloid that binds most herbicides is organic matter (OM), however clay minerals (CM) and metallic hydrous oxides are more retentive for cationic, phosphoric, and arsenic acid compounds. Weakly basic herbicides bind to both organic and inorganic soil colloids. The soil organic carbon (OC) affinity coefficient (Koc) has become a common parameter for comparing herbicide binding in soil; however, because OM and OC determinations vary greatly between methods and laboratories, Koc values may vary greatly. This proposal discusses this issue and offers suggestions for obtaining the most accurate Kd, Freundlich constant (Kf), and Koc values for herbicides listed in the WSSA Herbicide Handbook and Supplement. Nomenclature: Readers are referred to the WSSA Herbicide Handbook and Supplement for the chemical names of the herbicides. |
doi_str_mv | 10.1614/0043-1745%282000%29048%5B0075%3AAPTSSS%5D2.0.CO%3B2 |
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Herbicides bind to various soil constituents to differing degrees. The universal soil colloid that binds most herbicides is organic matter (OM), however clay minerals (CM) and metallic hydrous oxides are more retentive for cationic, phosphoric, and arsenic acid compounds. Weakly basic herbicides bind to both organic and inorganic soil colloids. The soil organic carbon (OC) affinity coefficient (Koc) has become a common parameter for comparing herbicide binding in soil; however, because OM and OC determinations vary greatly between methods and laboratories, Koc values may vary greatly. This proposal discusses this issue and offers suggestions for obtaining the most accurate Kd, Freundlich constant (Kf), and Koc values for herbicides listed in the WSSA Herbicide Handbook and Supplement. Nomenclature: Readers are referred to the WSSA Herbicide Handbook and Supplement for the chemical names of the herbicides.</description><identifier>ISSN: 0043-1745</identifier><identifier>EISSN: 1550-2759</identifier><identifier>DOI: 10.1614/0043-1745%282000%29048%5B0075%3AAPTSSS%5D2.0.CO%3B2</identifier><language>eng</language><publisher>Weed Science Society of America</publisher><subject>Acid soils ; Agrology ; arsenic ; clay minerals ; Clay soils ; Coefficients ; groundwater ; herbicide binding ; herbicide movement ; herbicide retention ; herbicide sorption ; Herbicides ; Koc ; leaching potential ; mathematical models ; organic matter ; Organic soils ; oxides ; soil ; Soil biochemistry ; soil colloids ; soil organic carbon ; Soil organic matter ; Soil properties ; Soil water ; SOIL, AIR, AND WATER ; weed science</subject><ispartof>Weed science, 2000-01, Vol.48 (1), p.75-88</ispartof><rights>Weed Science Society of America</rights><rights>Copyright 1999 The Weed Science Society of America</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://bioone.org/doi/pdf/10.1614/0043-1745%282000%29048%5B0075%3AAPTSSS%5D2.0.CO%3B2$$EPDF$$P50$$Gbioone$$H</linktopdf><linktohtml>$$Uhttps://www.jstor.org/stable/4046160$$EHTML$$P50$$Gjstor$$H</linktohtml><link.rule.ids>314,776,780,799,4010,26957,27902,27903,27904,52341,57995,58228</link.rule.ids></links><search><creatorcontrib>Weber, Jerome B.</creatorcontrib><creatorcontrib>Wilkerson, Gail G.</creatorcontrib><creatorcontrib>Michael Linker, H.</creatorcontrib><creatorcontrib>Wilcut, John W.</creatorcontrib><creatorcontrib>Leidy, Ross B.</creatorcontrib><creatorcontrib>Senseman, Scott</creatorcontrib><creatorcontrib>Witt, William W.</creatorcontrib><creatorcontrib>Barrett, Michael</creatorcontrib><creatorcontrib>Vencill, William K.</creatorcontrib><creatorcontrib>Shaw, David R.</creatorcontrib><creatorcontrib>Mueller, Thomas C.</creatorcontrib><creatorcontrib>Miller, Donnie K.</creatorcontrib><creatorcontrib>Brecke, Barry J.</creatorcontrib><creatorcontrib>Talbert, Ronald E.</creatorcontrib><creatorcontrib>Peeper, Thomas F.</creatorcontrib><title>A proposal to standardize soil/solution herbicide distribution coefficients</title><title>Weed science</title><description>Herbicide soil/solution distribution coefficients (Kd) are used in mathematical models to predict the movement of herbicides in soil and groundwater. Herbicides bind to various soil constituents to differing degrees. The universal soil colloid that binds most herbicides is organic matter (OM), however clay minerals (CM) and metallic hydrous oxides are more retentive for cationic, phosphoric, and arsenic acid compounds. Weakly basic herbicides bind to both organic and inorganic soil colloids. The soil organic carbon (OC) affinity coefficient (Koc) has become a common parameter for comparing herbicide binding in soil; however, because OM and OC determinations vary greatly between methods and laboratories, Koc values may vary greatly. This proposal discusses this issue and offers suggestions for obtaining the most accurate Kd, Freundlich constant (Kf), and Koc values for herbicides listed in the WSSA Herbicide Handbook and Supplement. Nomenclature: Readers are referred to the WSSA Herbicide Handbook and Supplement for the chemical names of the herbicides.</description><subject>Acid soils</subject><subject>Agrology</subject><subject>arsenic</subject><subject>clay minerals</subject><subject>Clay soils</subject><subject>Coefficients</subject><subject>groundwater</subject><subject>herbicide binding</subject><subject>herbicide movement</subject><subject>herbicide retention</subject><subject>herbicide sorption</subject><subject>Herbicides</subject><subject>Koc</subject><subject>leaching potential</subject><subject>mathematical models</subject><subject>organic matter</subject><subject>Organic soils</subject><subject>oxides</subject><subject>soil</subject><subject>Soil biochemistry</subject><subject>soil colloids</subject><subject>soil organic carbon</subject><subject>Soil organic matter</subject><subject>Soil properties</subject><subject>Soil water</subject><subject>SOIL, AIR, AND WATER</subject><subject>weed science</subject><issn>0043-1745</issn><issn>1550-2759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNo90E1Lw0AQBuBFFKzVfyCYS45pZz-TxVOsn1iokva8bJpd3RKzJRsP-utNjPY0MPPywjwIXWOYYYHZHIDRBKeMxyQjABATCSyL-Q1AymOa5y_roihifktmMFusYnpDjtAEcw4JSbk8RpNDwyk6C2EHgAXBcoKe82jf-r0Puo46H4VON5VuK_dtouBdPQ--_uycb6J305Zu6yoTVS50rSvH9dYba_u9abpwjk6sroO5-JtTtLm_Wy8ek-Xq4WmRL5MSYwmJ5SkmxjBqKqupkKkQhhkmSszYNtVCE8CllZlgBHgGsiJMZ7QymeXGpBmhU3Q59u5C51u1b92Hbr8UAyawgP58NZ6t9kq_tS6oTdF38v5pSSUdEq9jonTeN-bQgEEN3GrAUgOWGrnVL7caudU_t-q5FajFSvXc9AeADXUS</recordid><startdate>200001</startdate><enddate>200001</enddate><creator>Weber, Jerome B.</creator><creator>Wilkerson, Gail G.</creator><creator>Michael Linker, H.</creator><creator>Wilcut, John W.</creator><creator>Leidy, Ross B.</creator><creator>Senseman, Scott</creator><creator>Witt, William W.</creator><creator>Barrett, Michael</creator><creator>Vencill, William K.</creator><creator>Shaw, David R.</creator><creator>Mueller, Thomas C.</creator><creator>Miller, Donnie K.</creator><creator>Brecke, Barry J.</creator><creator>Talbert, Ronald E.</creator><creator>Peeper, Thomas F.</creator><general>Weed Science Society of America</general><scope>FBQ</scope></search><sort><creationdate>200001</creationdate><title>A proposal to standardize soil/solution herbicide distribution coefficients</title><author>Weber, Jerome B. ; Wilkerson, Gail G. ; Michael Linker, H. ; Wilcut, John W. ; Leidy, Ross B. ; Senseman, Scott ; Witt, William W. ; Barrett, Michael ; Vencill, William K. ; Shaw, David R. ; Mueller, Thomas C. ; Miller, Donnie K. ; Brecke, Barry J. ; Talbert, Ronald E. ; Peeper, Thomas F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-b1190-f5712ee43edfa369766e4e46b144c7a6a201bf9864205809d24a83de8f5ee7823</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>Acid soils</topic><topic>Agrology</topic><topic>arsenic</topic><topic>clay minerals</topic><topic>Clay soils</topic><topic>Coefficients</topic><topic>groundwater</topic><topic>herbicide binding</topic><topic>herbicide movement</topic><topic>herbicide retention</topic><topic>herbicide sorption</topic><topic>Herbicides</topic><topic>Koc</topic><topic>leaching potential</topic><topic>mathematical models</topic><topic>organic matter</topic><topic>Organic soils</topic><topic>oxides</topic><topic>soil</topic><topic>Soil biochemistry</topic><topic>soil colloids</topic><topic>soil organic carbon</topic><topic>Soil organic matter</topic><topic>Soil properties</topic><topic>Soil water</topic><topic>SOIL, AIR, AND WATER</topic><topic>weed science</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Weber, Jerome B.</creatorcontrib><creatorcontrib>Wilkerson, Gail G.</creatorcontrib><creatorcontrib>Michael Linker, H.</creatorcontrib><creatorcontrib>Wilcut, John W.</creatorcontrib><creatorcontrib>Leidy, Ross B.</creatorcontrib><creatorcontrib>Senseman, Scott</creatorcontrib><creatorcontrib>Witt, William W.</creatorcontrib><creatorcontrib>Barrett, Michael</creatorcontrib><creatorcontrib>Vencill, William K.</creatorcontrib><creatorcontrib>Shaw, David R.</creatorcontrib><creatorcontrib>Mueller, Thomas C.</creatorcontrib><creatorcontrib>Miller, Donnie K.</creatorcontrib><creatorcontrib>Brecke, Barry J.</creatorcontrib><creatorcontrib>Talbert, Ronald E.</creatorcontrib><creatorcontrib>Peeper, Thomas F.</creatorcontrib><collection>AGRIS</collection><jtitle>Weed science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Weber, Jerome B.</au><au>Wilkerson, Gail G.</au><au>Michael Linker, H.</au><au>Wilcut, John W.</au><au>Leidy, Ross B.</au><au>Senseman, Scott</au><au>Witt, William W.</au><au>Barrett, Michael</au><au>Vencill, William K.</au><au>Shaw, David R.</au><au>Mueller, Thomas C.</au><au>Miller, Donnie K.</au><au>Brecke, Barry J.</au><au>Talbert, Ronald E.</au><au>Peeper, Thomas F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A proposal to standardize soil/solution herbicide distribution coefficients</atitle><jtitle>Weed science</jtitle><date>2000-01</date><risdate>2000</risdate><volume>48</volume><issue>1</issue><spage>75</spage><epage>88</epage><pages>75-88</pages><issn>0043-1745</issn><eissn>1550-2759</eissn><abstract>Herbicide soil/solution distribution coefficients (Kd) are used in mathematical models to predict the movement of herbicides in soil and groundwater. Herbicides bind to various soil constituents to differing degrees. The universal soil colloid that binds most herbicides is organic matter (OM), however clay minerals (CM) and metallic hydrous oxides are more retentive for cationic, phosphoric, and arsenic acid compounds. Weakly basic herbicides bind to both organic and inorganic soil colloids. The soil organic carbon (OC) affinity coefficient (Koc) has become a common parameter for comparing herbicide binding in soil; however, because OM and OC determinations vary greatly between methods and laboratories, Koc values may vary greatly. This proposal discusses this issue and offers suggestions for obtaining the most accurate Kd, Freundlich constant (Kf), and Koc values for herbicides listed in the WSSA Herbicide Handbook and Supplement. Nomenclature: Readers are referred to the WSSA Herbicide Handbook and Supplement for the chemical names of the herbicides.</abstract><pub>Weed Science Society of America</pub><doi>10.1614/0043-1745%282000%29048%5B0075%3AAPTSSS%5D2.0.CO%3B2</doi><tpages>14</tpages></addata></record> |
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subjects | Acid soils Agrology arsenic clay minerals Clay soils Coefficients groundwater herbicide binding herbicide movement herbicide retention herbicide sorption Herbicides Koc leaching potential mathematical models organic matter Organic soils oxides soil Soil biochemistry soil colloids soil organic carbon Soil organic matter Soil properties Soil water SOIL, AIR, AND WATER weed science |
title | A proposal to standardize soil/solution herbicide distribution coefficients |
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