Thermochemistry and Thermodynamics of Ion Exchange in a Crystalline Exchange Medium

A simple, robust calorimeter has been constructed and used to study the heats of exchange of the ion pairs Li ⇌ Na, K ⇌ Na, Rb ⇌ Na, Cs ⇌ Na, and Ca ⇌ 2Na in Linde sieve 4 A, and parallel measurements have been made of the exchange equilibria. In all cases the thermochemical and equilibrium measurem...

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Veröffentlicht in:Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences Mathematical and physical sciences, 1963-05, Vol.273 (1353), p.180-197
Hauptverfasser: Barrer, Richard Maling, Rees, L. V. C., Ward, D. J.
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Sprache:eng
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