Bifunctional Lewis Acids. Synthesis and Olefin Polymerization Chemistry of the 1,1-Di[bis(perfluorophenyl)boryl]alkenes RCHC[B(C6F5)2]2 (R = t-Bu, C6H5, C6F5)

The synthesis and characterization, including crystallographic analysis, of the bifunctional boranes RCHC[B(C6F5)2]2 (R = t-C4H9, 1a; C6H5, 1b; C6F5, 1c) by regioselective hydroboration of the corresponding 1-boraalkynes using HB(C6F5)2 are reported herein. Compounds 1a and 1b have been screened as...

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Veröffentlicht in:Organometallics 1998-08, Vol.17 (16), p.3557-3566
Hauptverfasser: Köhler, Katrin, Piers, Warren E, Jarvis, Adam P, Xin, S, Feng, Y, Bravakis, A. M, Collins, Scott, Clegg, William, Yap, Glenn P. A, Marder, Todd B
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Sprache:eng
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