Thermodynamics and Kinetics of CO2 Adsorption on Dehydrated Palladium/Cobalt-Based Cyanogels:  A Highly Selective, Fully Reversible System for CO2 Storage

Carbon dioxide is selectively adsorbed on cyanide-bridged palladium/cobalt gels, synthesized from aqueous solutions of Na2PdCl4 and K3[Co(CN)6]. The cyanide bridges, connecting the palladium and cobalt metal centers, are characteristic of these gels; hence, these gels are termed cyanogels. The therm...

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Veröffentlicht in:Langmuir 2002-10, Vol.18 (20), p.7694-7698
Hauptverfasser: Deshpande, Rahul S, Sharp-Goldman, Stefanie L, Bocarsly, Andrew B
Format: Artikel
Sprache:eng
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