Cyclometalated Compounds. XVI. Double Cyclopalladations of Bis(2-pyridyloxy)naphthalenes. Kinetic versus Thermodynamic Control of Regiospecificity

A systematic study of the cyclopalladation reactions of bis(2-pyridyloxy)naphthalenes is described. On the basis of a kinetic preference for reaction at the 1-position, over thermodynamically favored reaction in the 3-position, a diverse range of doubly cyclopalladated compounds has been prepared, i...

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Veröffentlicht in:	Organometallics 2003-03, Vol.22 (6), p.1281-1292
Hauptverfasser:	O'Keef, Brendan J, Steel, Peter J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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