Preparation and NMR Spectra of the (Trifluoromethyl)argentates(III) [Ag(CF3) n X4-n ]-, with X = CN (n = 1−3), CH3, C⋮CC6H11, Cl, Br (n = 2, 3), and I (n = 3), and of Related Silver(III) Compounds. Structures of [PPh4][trans-Ag(CF3)2(CN)2] and [PPh4][Ag(CF3)3(CH3)]

Trifluoromethylation of [Ag(CN)2]- with (CF3)2Cd·diglyme yields [Ag(CF3)(CN)]-. The anion is readily oxidized by bromine to the argentates(III), [Ag(CF3)n(CN)4-n ]-, n = 1−4. The stability of these species decreases with an increasing number of CN groups. Halogenation of these complexes with acetyl...

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Veröffentlicht in:	Inorganic chemistry 1997-03, Vol.36 (7), p.1464-1475
Hauptverfasser:	Eujen, Reint, Hoge, Berthold, Brauer, David J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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